Zinc‐Incorporated Microporous Molecular Sieve for Mild Catalytic Hydrolysis of γ‐Valerolactone: A New Selective Route for Biomass Conversion

Wei‐Che Lin; Lin Ye; Simson Wu; Tsz Woon Benedict Lo; Yung‐Kang Peng; Pu Zhao; Ian McPherson; Shik Chi Edman Tsang

doi:10.1002/cssc.201802079

Zinc‐Incorporated Microporous Molecular Sieve for Mild Catalytic Hydrolysis of γ‐Valerolactone: A New Selective Route for Biomass Conversion

Wei‐Che Lin
, Lin Ye
, Simson Wu
, Tsz Woon Benedict Lo
, Yung‐Kang Peng
, Pu Zhao
, Ian McPherson
, Shik Chi Edman Tsang

Research output: Journal article publication › Journal article › Academic research › peer-review

13 Citations (Scopus)

Abstract

γ-Valerolactone (GVL) is regarded as a key platform molecule in the production of fine chemicals such as pentenoic acid (PA) from biomass. Although PA is believed to be the key intermediate in solid-acid-catalyzed reactions of GVL, due to subsequent facile decarboxylation reactions further alkene products are formed. Here, by tailoring the acidity of Brønsted acid sites in an aluminophosphate (AlPO) molecular sieve through incorporation of Zn²⁺ into the framework, we access a new selective and effective catalyst for GVL conversion to PA.

Original language	English
Pages (from-to)	4214-4218
Number of pages	5
Journal	ChemSusChem
Volume	11
Issue number	24
DOIs	https://doi.org/10.1002/cssc.201802079
Publication status	Published - 20 Dec 2018

Keywords

aluminophosphate
mild hydrolysis
pentenoic acid
valerolactone
zinc

ASJC Scopus subject areas

Environmental Chemistry
General Chemical Engineering
General Materials Science
General Energy

More information

10.1002/cssc.201802079

Cite this

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title = "Zinc‐Incorporated Microporous Molecular Sieve for Mild Catalytic Hydrolysis of γ‐Valerolactone: A New Selective Route for Biomass Conversion",

abstract = "γ-Valerolactone (GVL) is regarded as a key platform molecule in the production of fine chemicals such as pentenoic acid (PA) from biomass. Although PA is believed to be the key intermediate in solid-acid-catalyzed reactions of GVL, due to subsequent facile decarboxylation reactions further alkene products are formed. Here, by tailoring the acidity of Br{\o}nsted acid sites in an aluminophosphate (AlPO) molecular sieve through incorporation of Zn2+ into the framework, we access a new selective and effective catalyst for GVL conversion to PA.",

keywords = "aluminophosphate, mild hydrolysis, pentenoic acid, valerolactone, zinc",

author = "Wei‐Che Lin and Lin Ye and Simson Wu and Lo, \{Tsz Woon Benedict\} and Yung‐Kang Peng and Pu Zhao and Ian McPherson and Tsang, \{Shik Chi Edman\}",

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doi = "10.1002/cssc.201802079",

language = "English",

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T1 - Zinc‐Incorporated Microporous Molecular Sieve for Mild Catalytic Hydrolysis of γ‐Valerolactone: A New Selective Route for Biomass Conversion

AU - Lin, Wei‐Che

AU - Ye, Lin

AU - Wu, Simson

AU - Lo, Tsz Woon Benedict

AU - Peng, Yung‐Kang

AU - Zhao, Pu

AU - McPherson, Ian

AU - Tsang, Shik Chi Edman

PY - 2018/12/20

Y1 - 2018/12/20

N2 - γ-Valerolactone (GVL) is regarded as a key platform molecule in the production of fine chemicals such as pentenoic acid (PA) from biomass. Although PA is believed to be the key intermediate in solid-acid-catalyzed reactions of GVL, due to subsequent facile decarboxylation reactions further alkene products are formed. Here, by tailoring the acidity of Brønsted acid sites in an aluminophosphate (AlPO) molecular sieve through incorporation of Zn2+ into the framework, we access a new selective and effective catalyst for GVL conversion to PA.

AB - γ-Valerolactone (GVL) is regarded as a key platform molecule in the production of fine chemicals such as pentenoic acid (PA) from biomass. Although PA is believed to be the key intermediate in solid-acid-catalyzed reactions of GVL, due to subsequent facile decarboxylation reactions further alkene products are formed. Here, by tailoring the acidity of Brønsted acid sites in an aluminophosphate (AlPO) molecular sieve through incorporation of Zn2+ into the framework, we access a new selective and effective catalyst for GVL conversion to PA.

KW - aluminophosphate

KW - mild hydrolysis

KW - pentenoic acid

KW - valerolactone

KW - zinc

UR - https://www.scopus.com/pages/publications/85056628224

U2 - 10.1002/cssc.201802079

DO - 10.1002/cssc.201802079

M3 - Journal article

C2 - 30286279

AN - SCOPUS:85056628224

SN - 1864-5631

VL - 11

SP - 4214

EP - 4218

JO - ChemSusChem

JF - ChemSusChem

IS - 24

ER -

Zinc‐Incorporated Microporous Molecular Sieve for Mild Catalytic Hydrolysis of γ‐Valerolactone: A New Selective Route for Biomass Conversion

Abstract

Keywords

ASJC Scopus subject areas

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