Water-soluble Tb3+and Eu3+complexes based on task-specific ionic liquid ligands and their application in luminescent poly(vinyl alcohol) films

Qing Feng Li; Dan Yue; Gen Wu Ge; Xiaodi Du; Yanchuan Gong; Zhenling Wang; Jianhua Hao

doi:10.1039/c5dt02555a

Water-soluble Tb³⁺and Eu³⁺complexes based on task-specific ionic liquid ligands and their application in luminescent poly(vinyl alcohol) films

Qing Feng Li, Dan Yue, Gen Wu Ge, Xiaodi Du, Yanchuan Gong, Zhenling Wang, Jianhua Hao

Research output: Journal article publication › Journal article › Academic research › peer-review

36 Citations (Scopus)

Abstract

Novel water-soluble lanthanide complexes (Ln(IMI-DPA)3) have been synthesized using the task-specific ionic liquid consisting of a dipicolinic acid motif as the sensitizer of lanthanide luminescence. In Ln(IMI-DPA)3, Ln3+ions are in 9-fold coordination through six carboxylate oxygen atoms and three nitrogen atoms in pyridine units, and the water molecule is excluded from the coordination sphere of the lanthanides. It is found that Ln(IMI-DPA)3possess bright luminescence, long luminescence lifetime in aqueous solution, high thermal stability and good water solubility. Furthermore, these complexes can be incorporated into water-soluble poly(vinyl alcohol) (PVA) matrixes to obtain highly luminescent, transparent and flexible PVA composite films. The emission colors of the films can be tuned from red, orange, yellow, light green, green to white light by regulating the concentration of the various luminescent components.

Original language	English
Pages (from-to)	16810-16817
Number of pages	8
Journal	Dalton Transactions
Volume	44
Issue number	38
DOIs	https://doi.org/10.1039/c5dt02555a
Publication status	Published - 20 Aug 2015

ASJC Scopus subject areas

Inorganic Chemistry

More information

10.1039/c5dt02555a

Cite this

@article{15e8b98a0a8f43bc84ba080a060ec722,

title = "Water-soluble Tb3+and Eu3+complexes based on task-specific ionic liquid ligands and their application in luminescent poly(vinyl alcohol) films",

abstract = "Novel water-soluble lanthanide complexes (Ln(IMI-DPA)3) have been synthesized using the task-specific ionic liquid consisting of a dipicolinic acid motif as the sensitizer of lanthanide luminescence. In Ln(IMI-DPA)3, Ln3+ions are in 9-fold coordination through six carboxylate oxygen atoms and three nitrogen atoms in pyridine units, and the water molecule is excluded from the coordination sphere of the lanthanides. It is found that Ln(IMI-DPA)3possess bright luminescence, long luminescence lifetime in aqueous solution, high thermal stability and good water solubility. Furthermore, these complexes can be incorporated into water-soluble poly(vinyl alcohol) (PVA) matrixes to obtain highly luminescent, transparent and flexible PVA composite films. The emission colors of the films can be tuned from red, orange, yellow, light green, green to white light by regulating the concentration of the various luminescent components.",

author = "Li, {Qing Feng} and Dan Yue and Ge, {Gen Wu} and Xiaodi Du and Yanchuan Gong and Zhenling Wang and Jianhua Hao",

year = "2015",

month = aug,

day = "20",

doi = "10.1039/c5dt02555a",

language = "English",

volume = "44",

pages = "16810--16817",

journal = "Dalton Transactions",

issn = "1477-9226",

publisher = "Royal Society of Chemistry",

number = "38",

}

TY - JOUR

T1 - Water-soluble Tb3+and Eu3+complexes based on task-specific ionic liquid ligands and their application in luminescent poly(vinyl alcohol) films

AU - Li, Qing Feng

AU - Yue, Dan

AU - Ge, Gen Wu

AU - Du, Xiaodi

AU - Gong, Yanchuan

AU - Wang, Zhenling

AU - Hao, Jianhua

PY - 2015/8/20

Y1 - 2015/8/20

N2 - Novel water-soluble lanthanide complexes (Ln(IMI-DPA)3) have been synthesized using the task-specific ionic liquid consisting of a dipicolinic acid motif as the sensitizer of lanthanide luminescence. In Ln(IMI-DPA)3, Ln3+ions are in 9-fold coordination through six carboxylate oxygen atoms and three nitrogen atoms in pyridine units, and the water molecule is excluded from the coordination sphere of the lanthanides. It is found that Ln(IMI-DPA)3possess bright luminescence, long luminescence lifetime in aqueous solution, high thermal stability and good water solubility. Furthermore, these complexes can be incorporated into water-soluble poly(vinyl alcohol) (PVA) matrixes to obtain highly luminescent, transparent and flexible PVA composite films. The emission colors of the films can be tuned from red, orange, yellow, light green, green to white light by regulating the concentration of the various luminescent components.

AB - Novel water-soluble lanthanide complexes (Ln(IMI-DPA)3) have been synthesized using the task-specific ionic liquid consisting of a dipicolinic acid motif as the sensitizer of lanthanide luminescence. In Ln(IMI-DPA)3, Ln3+ions are in 9-fold coordination through six carboxylate oxygen atoms and three nitrogen atoms in pyridine units, and the water molecule is excluded from the coordination sphere of the lanthanides. It is found that Ln(IMI-DPA)3possess bright luminescence, long luminescence lifetime in aqueous solution, high thermal stability and good water solubility. Furthermore, these complexes can be incorporated into water-soluble poly(vinyl alcohol) (PVA) matrixes to obtain highly luminescent, transparent and flexible PVA composite films. The emission colors of the films can be tuned from red, orange, yellow, light green, green to white light by regulating the concentration of the various luminescent components.

UR - http://www.scopus.com/inward/record.url?scp=84942279899&partnerID=8YFLogxK

U2 - 10.1039/c5dt02555a

DO - 10.1039/c5dt02555a

M3 - Journal article

SN - 1477-9226

VL - 44

SP - 16810

EP - 16817

JO - Dalton Transactions

JF - Dalton Transactions

IS - 38

ER -

Water-soluble Tb³⁺and Eu³⁺complexes based on task-specific ionic liquid ligands and their application in luminescent poly(vinyl alcohol) films

Abstract

ASJC Scopus subject areas

More information

Other files and links

Fingerprint

Cite this