Visible light photocatalytic one pot synthesis of: Z -arylvinyl halides from e -arylvinyl acids with N -halosuccinimide

Qiong Yu; Kun Yi Yu; Cai Feng Xu; Man Kin Wong

doi:10.1039/d1ra08753c

Visible light photocatalytic one pot synthesis of: Z -arylvinyl halides from e -arylvinyl acids with N -halosuccinimide

Qiong Yu, Kun Yi Yu, Cai Feng Xu, Man Kin Wong

Research output: Journal article publication › Journal article › Academic research › peer-review

1 Citation (Scopus)

Abstract

An efficient visible light photocatalytic strategy to synthesize thermodynamically less stable Z-arylvinyl halides (with up to >99/1 Z/E ratio and 86% yield) was developed. The reaction combined base-mediated halodecarboxylation of E-arylvinyl acids with N-halosuccinimide and visible light Ir-photocatalyzed isomerization of E-arylvinyl halides in a one pot sequential catalytic process.

Original language	English
Pages (from-to)	3931-3934
Number of pages	4
Journal	RSC Advances
Volume	12
Issue number	7
DOIs	https://doi.org/10.1039/d1ra08753c
Publication status	Published - 31 Jan 2022

ASJC Scopus subject areas

General Chemistry
General Chemical Engineering

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10.1039/d1ra08753c

http://hdl.handle.net/10397/96473

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title = "Visible light photocatalytic one pot synthesis of: Z -arylvinyl halides from e -arylvinyl acids with N -halosuccinimide",

abstract = "An efficient visible light photocatalytic strategy to synthesize thermodynamically less stable Z-arylvinyl halides (with up to >99/1 Z/E ratio and 86% yield) was developed. The reaction combined base-mediated halodecarboxylation of E-arylvinyl acids with N-halosuccinimide and visible light Ir-photocatalyzed isomerization of E-arylvinyl halides in a one pot sequential catalytic process.",

author = "Qiong Yu and Yu, {Kun Yi} and Xu, {Cai Feng} and Wong, {Man Kin}",

note = "Funding Information: We gratefully acknowledge the nancial support from the Shenzhen Science and Technology Innovation Commission (JCYJ20170818104257975), the State Key Laboratory of Chemical Biology and Drug Discovery, and The Hong Kong Polytechnic University (G-ZVQZ). Publisher Copyright: {\textcopyright} The Royal Society of Chemistry.",

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doi = "10.1039/d1ra08753c",

language = "English",

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AU - Yu, Qiong

AU - Yu, Kun Yi

AU - Xu, Cai Feng

AU - Wong, Man Kin

N1 - Funding Information: We gratefully acknowledge the nancial support from the Shenzhen Science and Technology Innovation Commission (JCYJ20170818104257975), the State Key Laboratory of Chemical Biology and Drug Discovery, and The Hong Kong Polytechnic University (G-ZVQZ). Publisher Copyright: © The Royal Society of Chemistry.

PY - 2022/1/31

Y1 - 2022/1/31

N2 - An efficient visible light photocatalytic strategy to synthesize thermodynamically less stable Z-arylvinyl halides (with up to >99/1 Z/E ratio and 86% yield) was developed. The reaction combined base-mediated halodecarboxylation of E-arylvinyl acids with N-halosuccinimide and visible light Ir-photocatalyzed isomerization of E-arylvinyl halides in a one pot sequential catalytic process.

AB - An efficient visible light photocatalytic strategy to synthesize thermodynamically less stable Z-arylvinyl halides (with up to >99/1 Z/E ratio and 86% yield) was developed. The reaction combined base-mediated halodecarboxylation of E-arylvinyl acids with N-halosuccinimide and visible light Ir-photocatalyzed isomerization of E-arylvinyl halides in a one pot sequential catalytic process.

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U2 - 10.1039/d1ra08753c

DO - 10.1039/d1ra08753c

M3 - Journal article

AN - SCOPUS:85124422343

SN - 2046-2069

VL - 12

SP - 3931

EP - 3934

JO - RSC Advances

JF - RSC Advances

IS - 7

ER -

Visible light photocatalytic one pot synthesis of: Z -arylvinyl halides from e -arylvinyl acids with N -halosuccinimide

Abstract

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