Vinylidene and carbyne complexes derived from the reactions of OsCl(PPh3)(PCP) (PCP = 2,6-(PPh2CH2)2C6H3) with terminal acetylenes

Ting Bin Wen, Yuk King Cheung, Junzhi Yao, Wing Tak Wong, Zhong Yuan Zhou, Guochen Jia

Research output: Journal article publicationJournal articleAcademic researchpeer-review

58 Citations (Scopus)

Abstract

Treatment of OsCl2(PPh3)3with 1,3-(PPh2CH2)2C6H4led to the formation of the coordinatively unsaturated complex OsCl(PPh3)(PCP) (PCP = 2,6-(PPh2CH2)2C6H3). Reactions of OsCl(PPh3)(PCP) with RC triple bond CH (R = Ph, t-Bu, C(OH)Ph2) gave OsCl(double bond C double bond CHR)(PPh3)(PCP). Treatment of OsCl(double bond C double bond CHPh)(PPh3)(PCP) and OsCl(double bond C double bond CHC(OH)Ph2)(PPh3)(PCP) with HCl produced the carbyne complexes OsCl2(triple bond CCH2Ph)(PCP) and OsCl2(triple bond CCH double bond CPh2)(PCP), respectively. The solid-state structures of OsCl(PPh3)(PCP) and OsCl(double bond C double bond CHPh)(PPh3)-(PCP) have been determined by X-ray diffraction.
Original languageEnglish
Pages (from-to)3803-3809
Number of pages7
JournalOrganometallics
Volume19
Issue number19
Publication statusPublished - 18 Sep 2000

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

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