Vibrational reorganizational energies of the MLCT transition in Pt(dppm)2(PhC≡C)2and the MMLCT transition in [Pt2(μ-dppm)2(μ-PhC≡C)(PhC≡C)2]+

Wai Ming Kwok, David Lee Phillips, Phyllis Kok Yan Yeung, Vivian Wing Wah Yam

Research output: Journal article publicationJournal articleAcademic researchpeer-review

27 Citations (Scopus)

Abstract

We have obtained resonance Raman spectra including absolute Raman cross section measurements taken with excitation wavelengths within the MLCT absorption band of Pt(dppm)2(PhC≡C)2and the MMLCT absorption band of [Pt2(μ-dppm)2(μ-PhC≡C)(PhC≡C)2]+. We have simultaneously modeled the absolute absorption and resonance Raman intensities to obtain an estimate of the vibrational reorganizational energies associated with the MLCT transition of Pt(dppm)2(PhC≡C)2as well as the homogeneous and inhomogeneous broadening contributions to the absorption band. We compare the experimental resonance Raman spectra of the dimer MMLCT transition to those of the MLCT monomer system.
Original languageEnglish
Pages (from-to)699-708
Number of pages10
JournalChemical Physics Letters
Volume262
Issue number6
DOIs
Publication statusPublished - 29 Nov 1996
Externally publishedYes

ASJC Scopus subject areas

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

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