Transition Metal Doped Smart Glass with Pressure and Temperature Sensitive Luminescence

Shichao Lv, B. Shanmugavelu, Yunpeng Wang, Qiannan Mao, Yujun Zhao, Yongze Yu, Jianhua Hao, Qinyuan Zhang, Jianrong Qiu, Shifeng Zhou

Research output: Journal article publicationJournal articleAcademic researchpeer-review

25 Citations (Scopus)

Abstract

The development of future transparent intelligent systems demands smart glass with multifunctional sensing capabilities. Here, the realization of a smart glass with dual temperature and pressure sensing function by using Mn2+-doped nanostructured gallate glass for the first time is reported. The material exhibits exceptional temperature response in the range of 323–523 K and the maximal relative temperature sensitivity reaches as high as 2.51% K−1 at 523 K. The material is also sensitive to the pressure fluctuation and displays bright green pressure-induced luminescence. A combination of structural and optical analysis and theoretical calculation reveals that the local dopant orientation in nanodomain inside glass contributes to the previously unrealized sensing behavior. The critical factors governing the sensing performance are identified and the cooperative effects between the local chemical bonding and domain size contribute greatly to the remarkable enhancement of the sensitivity. The results highlight that the precise control over the doping process offers a great opportunity to design new smart glass.

Original languageEnglish
Article number1800881
JournalAdvanced Optical Materials
Volume6
Issue number21
DOIs
Publication statusPublished - 5 Nov 2018

Keywords

  • dopants
  • luminescence
  • optical active materials
  • smart glass

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Atomic and Molecular Physics, and Optics

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