Towards the high energy density batteries via fluoride ions shuttling in liquid electrolytes: A review

Saeed Shafiei Kaleibari; Qiang Ye; Meng Ni

doi:10.1002/er.8468

Towards the high energy density batteries via fluoride ions shuttling in liquid electrolytes: A review

Saeed Shafiei Kaleibari
, Qiang Ye
, Meng Ni

Research output: Journal article publication › Review article › Academic research › peer-review

7 Citations (Scopus)

Abstract

Fluorine, as the most electronegative element, provides the highest electrode potential when it undergoes redox reactions. Moreover, fluoride ion is intrinsically an excellent charge carrier in both electrolytes and electrode structures owing to its small size, low atomic weight, and good ionic mobility. Hence, batteries based on fluorine electrochemistry, the so-called fluoride ion batteries (FIBs), have recently been deemed as an alternative next-generation high energy density battery system. This article reviews the recent progress in FIBs based on liquid electrolytes. The mechanisms, advantages, and drawbacks of FIBs are discussed. In the end, the perspective illuminating the research directions for further development is presented.

Original language	English
Journal	International Journal of Energy Research
DOIs	https://doi.org/10.1002/er.8468
Publication status	Accepted/In press - Aug 2022

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

SDG 7 Affordable and Clean Energy

Keywords

anion based battery
fluoride ion battery (FIB)
fluoride salt concentration
fluorine chemistry
liquid electrolyte fluoride shuttle battery

ASJC Scopus subject areas

Renewable Energy, Sustainability and the Environment
Nuclear Energy and Engineering
Fuel Technology
Energy Engineering and Power Technology

More information

10.1002/er.8468

Cite this

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title = "Towards the high energy density batteries via fluoride ions shuttling in liquid electrolytes: A review",

abstract = "Fluorine, as the most electronegative element, provides the highest electrode potential when it undergoes redox reactions. Moreover, fluoride ion is intrinsically an excellent charge carrier in both electrolytes and electrode structures owing to its small size, low atomic weight, and good ionic mobility. Hence, batteries based on fluorine electrochemistry, the so-called fluoride ion batteries (FIBs), have recently been deemed as an alternative next-generation high energy density battery system. This article reviews the recent progress in FIBs based on liquid electrolytes. The mechanisms, advantages, and drawbacks of FIBs are discussed. In the end, the perspective illuminating the research directions for further development is presented.",

keywords = "anion based battery, fluoride ion battery (FIB), fluoride salt concentration, fluorine chemistry, liquid electrolyte fluoride shuttle battery",

author = "\{Shafiei Kaleibari\}, Saeed and Qiang Ye and Meng Ni",

note = "Funding Information: This work is financially supported by the National Natural Science Foundation of China through Project 51776120, and a grant from Collaborative Research Fund (CRF) (Project no. C5031‐20G) of Research Grant Council, University Grant Committee, HK SAR. Funding Information: Collaborative Research Fund (CRF), Grant/Award Number: C5031‐20G; National Natural Science Foundation of China, Grant/Award Number: 51776120 Funding information Publisher Copyright: {\textcopyright} 2022 John Wiley \& Sons Ltd.",

year = "2022",

month = aug,

doi = "10.1002/er.8468",

language = "English",

journal = "International Journal of Energy Research",

issn = "0363-907X",

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TY - JOUR

T1 - Towards the high energy density batteries via fluoride ions shuttling in liquid electrolytes

T2 - A review

AU - Shafiei Kaleibari, Saeed

AU - Ye, Qiang

AU - Ni, Meng

N1 - Funding Information: This work is financially supported by the National Natural Science Foundation of China through Project 51776120, and a grant from Collaborative Research Fund (CRF) (Project no. C5031‐20G) of Research Grant Council, University Grant Committee, HK SAR. Funding Information: Collaborative Research Fund (CRF), Grant/Award Number: C5031‐20G; National Natural Science Foundation of China, Grant/Award Number: 51776120 Funding information Publisher Copyright: © 2022 John Wiley & Sons Ltd.

PY - 2022/8

Y1 - 2022/8

N2 - Fluorine, as the most electronegative element, provides the highest electrode potential when it undergoes redox reactions. Moreover, fluoride ion is intrinsically an excellent charge carrier in both electrolytes and electrode structures owing to its small size, low atomic weight, and good ionic mobility. Hence, batteries based on fluorine electrochemistry, the so-called fluoride ion batteries (FIBs), have recently been deemed as an alternative next-generation high energy density battery system. This article reviews the recent progress in FIBs based on liquid electrolytes. The mechanisms, advantages, and drawbacks of FIBs are discussed. In the end, the perspective illuminating the research directions for further development is presented.

AB - Fluorine, as the most electronegative element, provides the highest electrode potential when it undergoes redox reactions. Moreover, fluoride ion is intrinsically an excellent charge carrier in both electrolytes and electrode structures owing to its small size, low atomic weight, and good ionic mobility. Hence, batteries based on fluorine electrochemistry, the so-called fluoride ion batteries (FIBs), have recently been deemed as an alternative next-generation high energy density battery system. This article reviews the recent progress in FIBs based on liquid electrolytes. The mechanisms, advantages, and drawbacks of FIBs are discussed. In the end, the perspective illuminating the research directions for further development is presented.

KW - anion based battery

KW - fluoride ion battery (FIB)

KW - fluoride salt concentration

KW - fluorine chemistry

KW - liquid electrolyte fluoride shuttle battery

UR - https://www.scopus.com/pages/publications/85135864817

U2 - 10.1002/er.8468

DO - 10.1002/er.8468

M3 - Review article

AN - SCOPUS:85135864817

SN - 0363-907X

JO - International Journal of Energy Research

JF - International Journal of Energy Research

ER -

Towards the high energy density batteries via fluoride ions shuttling in liquid electrolytes: A review

Abstract

UN SDGs

Keywords

ASJC Scopus subject areas

More information

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