TY - JOUR
T1 - Towards the high energy density batteries via fluoride ions shuttling in liquid electrolytes
T2 - A review
AU - Shafiei Kaleibari, Saeed
AU - Ye, Qiang
AU - Ni, Meng
N1 - Funding Information:
This work is financially supported by the National Natural Science Foundation of China through Project 51776120, and a grant from Collaborative Research Fund (CRF) (Project no. C5031‐20G) of Research Grant Council, University Grant Committee, HK SAR.
Funding Information:
Collaborative Research Fund (CRF), Grant/Award Number: C5031‐20G; National Natural Science Foundation of China, Grant/Award Number: 51776120 Funding information
Publisher Copyright:
© 2022 John Wiley & Sons Ltd.
PY - 2022/8
Y1 - 2022/8
N2 - Fluorine, as the most electronegative element, provides the highest electrode potential when it undergoes redox reactions. Moreover, fluoride ion is intrinsically an excellent charge carrier in both electrolytes and electrode structures owing to its small size, low atomic weight, and good ionic mobility. Hence, batteries based on fluorine electrochemistry, the so-called fluoride ion batteries (FIBs), have recently been deemed as an alternative next-generation high energy density battery system. This article reviews the recent progress in FIBs based on liquid electrolytes. The mechanisms, advantages, and drawbacks of FIBs are discussed. In the end, the perspective illuminating the research directions for further development is presented.
AB - Fluorine, as the most electronegative element, provides the highest electrode potential when it undergoes redox reactions. Moreover, fluoride ion is intrinsically an excellent charge carrier in both electrolytes and electrode structures owing to its small size, low atomic weight, and good ionic mobility. Hence, batteries based on fluorine electrochemistry, the so-called fluoride ion batteries (FIBs), have recently been deemed as an alternative next-generation high energy density battery system. This article reviews the recent progress in FIBs based on liquid electrolytes. The mechanisms, advantages, and drawbacks of FIBs are discussed. In the end, the perspective illuminating the research directions for further development is presented.
KW - anion based battery
KW - fluoride ion battery (FIB)
KW - fluoride salt concentration
KW - fluorine chemistry
KW - liquid electrolyte fluoride shuttle battery
UR - http://www.scopus.com/inward/record.url?scp=85135864817&partnerID=8YFLogxK
U2 - 10.1002/er.8468
DO - 10.1002/er.8468
M3 - Review article
AN - SCOPUS:85135864817
SN - 0363-907X
JO - International Journal of Energy Research
JF - International Journal of Energy Research
ER -