Time-resolved resonance Raman observation of the 2-fluorenylnitrenium ion reaction with guanosine to form a C8 intermediate

Pik Ying Chan; Wai Ming Kwok; Sze Kui Lam; Pauline Chiu; David Lee Phillips

doi:10.1021/ja0505651

Time-resolved resonance Raman observation of the 2-fluorenylnitrenium ion reaction with guanosine to form a C8 intermediate

Pik Ying Chan, Wai Ming Kwok, Sze Kui Lam, Pauline Chiu, David Lee Phillips

Research output: Journal article publication › Journal article › Academic research › peer-review

42 Citations (Scopus)

Abstract

Time-resolved resonance Raman spectroscopy was used to directly observe the reaction of the 2-fluorenylnitrenium ion with guanosine to produce a C8 intermediate species. Comparison of the Raman spectra with results of density functional theory calculations indicates the C8 intermediate forms two CN conjugated bonds in ring 1 of the guanosine moiety.

Original language	English
Pages (from-to)	8246-8247
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	127
Issue number	23
DOIs	https://doi.org/10.1021/ja0505651
Publication status	Published - 15 Jun 2005
Externally published	Yes

ASJC Scopus subject areas

Catalysis
Chemistry(all)
Biochemistry
Colloid and Surface Chemistry

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10.1021/ja0505651

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title = "Time-resolved resonance Raman observation of the 2-fluorenylnitrenium ion reaction with guanosine to form a C8 intermediate",

abstract = "Time-resolved resonance Raman spectroscopy was used to directly observe the reaction of the 2-fluorenylnitrenium ion with guanosine to produce a C8 intermediate species. Comparison of the Raman spectra with results of density functional theory calculations indicates the C8 intermediate forms two CN conjugated bonds in ring 1 of the guanosine moiety.",

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Time-resolved resonance Raman observation of the 2-fluorenylnitrenium ion reaction with guanosine to form a C8 intermediate. / Chan, Pik Ying; Kwok, Wai Ming; Lam, Sze Kui et al.
In: Journal of the American Chemical Society, Vol. 127, No. 23, 15.06.2005, p. 8246-8247.

Research output: Journal article publication › Journal article › Academic research › peer-review

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AU - Chan, Pik Ying

AU - Kwok, Wai Ming

AU - Lam, Sze Kui

AU - Chiu, Pauline

AU - Phillips, David Lee

PY - 2005/6/15

Y1 - 2005/6/15

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AB - Time-resolved resonance Raman spectroscopy was used to directly observe the reaction of the 2-fluorenylnitrenium ion with guanosine to produce a C8 intermediate species. Comparison of the Raman spectra with results of density functional theory calculations indicates the C8 intermediate forms two CN conjugated bonds in ring 1 of the guanosine moiety.

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JF - Journal of the American Chemical Society

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Time-resolved resonance Raman observation of the 2-fluorenylnitrenium ion reaction with guanosine to form a C8 intermediate

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