Thermally mendable epoxy resin strengthened with carbon nanofibres

This paper investigates the strengthening and toughening effects of carbon nanofibres (CNFs) on a self-healing thermoset/thermoplastic blend, i.e. an epoxy/poly (ε-caprolactone) (PCL) blend. The self-healing material system was prepared by polymer blending that produced a co-continuous phase-separated structure. The addition of CNFs altered the phase structures, leading to smaller domain sizes or even completely altering the phase separation mechanism, e.g. conversion from a co-continuous phase-separated structure to a particulate phase structure when the CNF content reached a certain level (0.3 wt% in this work). As the content of CNFs increased, the resulting nanocomposite became stronger and tougher, but the self-healing efficiency diminished; the optimal CNF content was found to be 0.2 wt%, which produced the highest strength, toughness and hardness, while achieving around 70% of healing efficiency.