The total reactive oxidized nitrogen levels and the partitioning between the individual species at six rural sites in eastern North America

D. D. Parrish, M. P. Buhr, M. Trainer, R. B. Norton, J. P. Shimshock, F. C. Fehsenfeld, K. G. Anlauf, J. W. Bottenheim, Y. Z. Tang, H. A. Wiebe, J. M. Roberts, R. L. Tanner, L. Newman, V. C. Bowersox, K. J. Olszyna, E. M. Bailey, M. O. Rodgers, T. Wang, H. Berresheim, U. K. RoychowdhuryK. L. Demerjian

Research output: Journal article publicationJournal articleAcademic researchpeer-review

147 Citations (Scopus)

Abstract

During the daytime the median NOY levels were 2 to 5 ppbv at all sites, which may be representative of rural areas in the populated regions of eastern North America. Each site showed variations in the NOY levels of an order of magnitude or more. Measurements from all of the sites are consistent with the major contributors to NOY being NOX (the sum of NO and NO2), PAN, and nitric acid with a minor contribution from aerosol nitrate. At the lower elevation sites the median [NOX] to [NOY] ratios were 70% or more during the night and declined to minima of 25 to 40% during the day. During the daytime the ranges of the median contributions of PAN and HNO3 to NOY were 12 to 25% and approximately 20 to 30%, respectively. The distributions of the contributions about these medians are discussed. Results from all of the sites are consistent with the individually measured species accounting for about 90% of the simultaneously measured NOY. -from Authors

Original languageEnglish
Pages (from-to)2927-2939
Number of pages13
JournalJournal of Geophysical Research
Volume98
Issue numberD2
DOIs
Publication statusPublished - 1 Jan 1993
Externally publishedYes

ASJC Scopus subject areas

  • Geophysics
  • Forestry
  • Oceanography
  • Aquatic Science
  • Ecology
  • Water Science and Technology
  • Soil Science
  • Geochemistry and Petrology
  • Earth-Surface Processes
  • Atmospheric Science
  • Earth and Planetary Sciences (miscellaneous)
  • Space and Planetary Science
  • Palaeontology

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