The effect of weak Brönsted acids on the electrocatalytic reduction of carbon dioxide by a rhenium tricarbonyl bipyridyl complex

Kwok Yin Wong, Wan Hung Chung, Chak Po Lau

Research output: Journal article publicationJournal articleAcademic researchpeer-review

78 Citations (Scopus)

Abstract

The effect of four weak Brönsted acids, 2,2,2-trifluoroethanol, phenol, methanol and water on the electrocatalytic reduction of CO2by [Re(bpy)(CO)3(py)]2+(bpy = 2,2′-bipyridine, py = pyridine) in acetonitrile was investigated. The addition of weak Brönsted acids enhances the rate of the catalytic process and improves the lifetime of the rhenium catalyst. Under the experimental conditions employed in this study, CO was produced as the only product with faradaic efficiency close to 100%. Kinetic analysis indicated that the reaction order in acid is 2. The Brönsted acids probably stabilise the rhenium-carbon dioxide intermediate through protonation and facilitate the cleavage of one of the C-O bonds to yield CO. The efficiency of the acid increases with its acidity. Thus, trifluoroethanol and phenol are more effective in enhancing the rate of catalysis than methanol and water. Even though the acid strength of water and methanol are very similar, water is much less effective in enhancing the rate of CO2reduction. This can be attributed to the relatively strong ligating property of water, which would compete with CO2for the binding site on rhenium.
Original languageEnglish
Pages (from-to)161-170
Number of pages10
JournalJournal of Electroanalytical Chemistry
Volume453
Issue number1-2
DOIs
Publication statusPublished - 14 Aug 1998

Keywords

  • Brönsted acid
  • Carbon dioxide
  • Electrocatalytic reduction
  • Rhenium complex

ASJC Scopus subject areas

  • Analytical Chemistry
  • Chemical Engineering(all)
  • Electrochemistry

Cite this