Temperature and Magnetic Field Induced Phase Transformation in Bulk and Composite Gd5Si2Ge2

  • Nersesse Nersessian
  • , Siu Wing Or
  • , Gregory P. Carman
  • , Wonyoung Choe
  • , Harry B. Radousky
  • , Vitalij K. Pecharsky
  • , Alexandra O. Pecharsky

Research output: Journal article publicationConference articleAcademic researchpeer-review

2 Citations (Scopus)

Abstract

A -1300ppm strain has been obtained in a [0-3], resin binder, Gd5Si2Ge2participate composite. The strain is a result of a temperature induced phase transformation from a high volume (high temperature, low magnetic field) monoclinic phase to a low volume (low temperature, high magnetic field) orthorhombic phase. The particles used in the composite were ball-milled from a bulk sample and were sieved to obtain a size distribution of ≤ 600μm. Bulk Gd5Si2Ge2was manufactured via arc melting and subsequently annealed at 1300°C for 1 hour to produce a textured, polycrystalline sample. The transformation temperatures of the bulk sample, as measured using a Differential Scanning Calorimeter (DSC), were Ms= -9.3°C, Mf= -14.6°C, As= -4.4°C, and Af= -1.2°C. The bulk sample was magnetically characterized using a SQUID magnetometer, and found to undergo a paramagnetic to ferromagnetic transition during the phase transformation, consistent with published results. The bulk sample was also found to possess a - 8000ppm volume magnetostriction, agreeing well with measured unit cell parameters of the different phases.
Original languageEnglish
Pages (from-to)25-30
Number of pages6
JournalProceedings of SPIE - The International Society for Optical Engineering
Volume5053
DOIs
Publication statusPublished - 27 Nov 2003
Externally publishedYes
EventPROCEEDINGS OF SPIE SPIE - The International Society for Optical Engineering: Smart Structures and Materials 2003 Active Materials: Behavior and Mechanics - San Diego, CA, United States
Duration: 3 Mar 20036 Mar 2003

Keywords

  • [0-3] Composites
  • Gd Si Ge 5 2 2
  • Phase transformationy
  • Volume Magnetostriction

ASJC Scopus subject areas

  • Electrical and Electronic Engineering
  • Condensed Matter Physics

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