Synthesis, structural characterization and solution dynamics of osmium-rhodium mixed-metal cluster [Os4Rh(μ-H)4(CO)132-NC5H4C2H2)]

Jasmine Po Kwan Lau, Wing Tak Wong

Research output: Journal article publicationJournal articleAcademic researchpeer-review

17 Citations (Scopus)

Abstract

Reaction of [Os3Rh(μ-H)3(CO)12] 1 with an excess amount of 2-vinylpyridine in refluxing CHCl3afforded a new cluster, [Os4Rh(μ-H)4(CO)13(η2-NC5H4C2H2)] 2, in moderate yield. A pair of isomers 2a and 2b, which differ in configuration of the metallated vinylpyridine exist in the solution of 2. Through the variable temperature EXSY experiment, the activation barrier (ΔG≠) for the isomerisation of 2 was determined to be 89.8 kJ mol-1.
Original languageEnglish
Pages (from-to)174-177
Number of pages4
JournalInorganic Chemistry Communications
Volume6
Issue number2
DOIs
Publication statusPublished - 1 Feb 2003
Externally publishedYes

Keywords

  • 2-Vinylpyridine
  • 2D EXSY-experiment
  • Osmium-Rhodium
  • X-ray crystallography

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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