Synthesis of self-detached nanoporous titanium-based metal oxide

F. Hu, Y. Wen, Kang Cheung Chan, Tai Man Yue, Y. Z. Zhou, S. L. Zhu, X. J. Yang

Research output: Journal article publicationJournal articleAcademic researchpeer-review

2 Citations (Scopus)

Abstract

In this study, self-detached nanoporous titanium-based metal oxide was synthesized for the first time by ultrafast anodization in a fluoride-free electrolyte containing 10% HNO3. The nanoporous oxide has through-holes with diameters ranging from 10 to 60 nm. The as-formed oxides are amorphous, and were transformed to crystalline structures by annealing. The performance of a dye sensitized solar cell using nanoporpous Ti-10Zr oxide (TZ10) was further studied. It was found that the TZ10 film could increase both the short-circuit current and the open-circuit photovoltage of the solar cell. The overall efficiency of the solar cell was 6.99%, an increase of 20.7% as compared to that using a pure TiO2 (P25) film.
Original languageEnglish
Pages (from-to)78-86
Number of pages9
JournalJournal of Solid State Chemistry
Volume229
Issue number1
DOIs
Publication statusPublished - 1 Jan 2015

Keywords

  • Dye sensitized solar cell
  • Fluoride-free solution
  • TiZr
  • Ultrafast anodization

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Condensed Matter Physics
  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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