Synthesis of ruthenium(II) 1,2-naphthoquinone-2-oxime complexes containing C16 long alkyl chain

Xiao Xia Liu; Wing Tak Wong; Ke Sun; Bao Yan Zhang; Lu Zhang

Synthesis of ruthenium(II) 1,2-naphthoquinone-2-oxime complexes containing C₁₆ long alkyl chain

Xiao Xia Liu, Wing Tak Wong, Ke Sun, Bao Yan Zhang, Lu Zhang

Research output: Journal article publication › Journal article › Academic research › peer-review

Abstract

C16 long alkyl chains containing complexes trans-,cis-[Ru(2-nqo) 2(CO)(spy)] (4) [(trans-NO, cis-O)], cis-,trans-[Ru(2-nqo) 2(CO)(spy)] (5) {(cis-NO, trans-O)}, cis-, cis-[Ru(2-nqo) 2-(CO) (spy)] (6) {(cis-NO, cis-O)} and trans-, trans-[Ru(2-nqo) 2(spy)2] (7) {(trans-NO, trans-O)} were synthesized by decarbonylated substitution of three isomers of ruthenium (II) carbonyl complexes of 1,2-naphthoquinone-2-oxime (2-nqo) trans-, cis-[Ru(2-nqo) 2(CO)2] (1), cis-, trans-[Ru(2-nqo)2(CO) 2] (2) and cis-, cis-[Ru(2-nqo)2(CO)2] (3). All the complexes were characterized by IR, UV-vis, FAB-MS and 1H- 1H COSY 1H NMR.

Original language	English
Pages (from-to)	2214-2219
Number of pages	6
Journal	Acta Chimica Sinica
Volume	60
Issue number	12
Publication status	Published - 1 Dec 2002
Externally published	Yes

Keywords

1,2-Naphthoquinone-2-oxime
Decarbonylated substitution
Ruthenium

ASJC Scopus subject areas

General Chemistry

Cite this

@article{2c25281892f94655b217a2d4565b597c,

title = "Synthesis of ruthenium(II) 1,2-naphthoquinone-2-oxime complexes containing C16 long alkyl chain",

abstract = "C16 long alkyl chains containing complexes trans-,cis-[Ru(2-nqo) 2(CO)(spy)] (4) [(trans-NO, cis-O)], cis-,trans-[Ru(2-nqo) 2(CO)(spy)] (5) {(cis-NO, trans-O)}, cis-, cis-[Ru(2-nqo) 2-(CO) (spy)] (6) {(cis-NO, cis-O)} and trans-, trans-[Ru(2-nqo) 2(spy)2] (7) {(trans-NO, trans-O)} were synthesized by decarbonylated substitution of three isomers of ruthenium (II) carbonyl complexes of 1,2-naphthoquinone-2-oxime (2-nqo) trans-, cis-[Ru(2-nqo) 2(CO)2] (1), cis-, trans-[Ru(2-nqo)2(CO) 2] (2) and cis-, cis-[Ru(2-nqo)2(CO)2] (3). All the complexes were characterized by IR, UV-vis, FAB-MS and 1H- 1H COSY 1H NMR.",

keywords = "1,2-Naphthoquinone-2-oxime, Decarbonylated substitution, Ruthenium",

author = "Liu, {Xiao Xia} and Wong, {Wing Tak} and Ke Sun and Zhang, {Bao Yan} and Lu Zhang",

year = "2002",

month = dec,

day = "1",

language = "English",

volume = "60",

pages = "2214--2219",

journal = "Acta Chimica Sinica",

issn = "0567-7351",

publisher = "Science Press",

number = "12",

}

TY - JOUR

T1 - Synthesis of ruthenium(II) 1,2-naphthoquinone-2-oxime complexes containing C16 long alkyl chain

AU - Liu, Xiao Xia

AU - Wong, Wing Tak

AU - Sun, Ke

AU - Zhang, Bao Yan

AU - Zhang, Lu

PY - 2002/12/1

Y1 - 2002/12/1

N2 - C16 long alkyl chains containing complexes trans-,cis-[Ru(2-nqo) 2(CO)(spy)] (4) [(trans-NO, cis-O)], cis-,trans-[Ru(2-nqo) 2(CO)(spy)] (5) {(cis-NO, trans-O)}, cis-, cis-[Ru(2-nqo) 2-(CO) (spy)] (6) {(cis-NO, cis-O)} and trans-, trans-[Ru(2-nqo) 2(spy)2] (7) {(trans-NO, trans-O)} were synthesized by decarbonylated substitution of three isomers of ruthenium (II) carbonyl complexes of 1,2-naphthoquinone-2-oxime (2-nqo) trans-, cis-[Ru(2-nqo) 2(CO)2] (1), cis-, trans-[Ru(2-nqo)2(CO) 2] (2) and cis-, cis-[Ru(2-nqo)2(CO)2] (3). All the complexes were characterized by IR, UV-vis, FAB-MS and 1H- 1H COSY 1H NMR.

AB - C16 long alkyl chains containing complexes trans-,cis-[Ru(2-nqo) 2(CO)(spy)] (4) [(trans-NO, cis-O)], cis-,trans-[Ru(2-nqo) 2(CO)(spy)] (5) {(cis-NO, trans-O)}, cis-, cis-[Ru(2-nqo) 2-(CO) (spy)] (6) {(cis-NO, cis-O)} and trans-, trans-[Ru(2-nqo) 2(spy)2] (7) {(trans-NO, trans-O)} were synthesized by decarbonylated substitution of three isomers of ruthenium (II) carbonyl complexes of 1,2-naphthoquinone-2-oxime (2-nqo) trans-, cis-[Ru(2-nqo) 2(CO)2] (1), cis-, trans-[Ru(2-nqo)2(CO) 2] (2) and cis-, cis-[Ru(2-nqo)2(CO)2] (3). All the complexes were characterized by IR, UV-vis, FAB-MS and 1H- 1H COSY 1H NMR.

KW - 1,2-Naphthoquinone-2-oxime

KW - Decarbonylated substitution

KW - Ruthenium

UR - http://www.scopus.com/inward/record.url?scp=0442264166&partnerID=8YFLogxK

M3 - Journal article

SN - 0567-7351

VL - 60

SP - 2214

EP - 2219

JO - Acta Chimica Sinica

JF - Acta Chimica Sinica

IS - 12

ER -

Synthesis of ruthenium(II) 1,2-naphthoquinone-2-oxime complexes containing C₁₆ long alkyl chain

Abstract

Keywords

ASJC Scopus subject areas

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