Synthesis of ruthenium(II) 1,2-naphthoquinone-2-oxime complexes containing C16 long alkyl chain

Xiao Xia Liu, Wing Tak Wong, Ke Sun, Bao Yan Zhang, Lu Zhang

Research output: Journal article publicationJournal articleAcademic researchpeer-review

2 Citations (Scopus)

Abstract

C16 long alkyl chains containing complexes trans-,cis-[Ru(2-nqo) 2(CO)(spy)] (4) [(trans-NO, cis-O)], cis-,trans-[Ru(2-nqo) 2(CO)(spy)] (5) {(cis-NO, trans-O)}, cis-, cis-[Ru(2-nqo) 2-(CO) (spy)] (6) {(cis-NO, cis-O)} and trans-, trans-[Ru(2-nqo) 2(spy)2] (7) {(trans-NO, trans-O)} were synthesized by decarbonylated substitution of three isomers of ruthenium (II) carbonyl complexes of 1,2-naphthoquinone-2-oxime (2-nqo) trans-, cis-[Ru(2-nqo) 2(CO)2] (1), cis-, trans-[Ru(2-nqo)2(CO) 2] (2) and cis-, cis-[Ru(2-nqo)2(CO)2] (3). All the complexes were characterized by IR, UV-vis, FAB-MS and 1H- 1H COSY 1H NMR.
Original languageEnglish
Pages (from-to)2214-2219
Number of pages6
JournalActa Chimica Sinica
Volume60
Issue number12
Publication statusPublished - 1 Dec 2002
Externally publishedYes

Keywords

  • 1,2-Naphthoquinone-2-oxime
  • Decarbonylated substitution
  • Ruthenium

ASJC Scopus subject areas

  • Chemistry(all)

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