Synthesis of novel selenium-containing osmium carbonyl clusters: X-ray structures of [Os5(μ-H) (CO)15(μ3-SePh)] and [Os6(μ-H)(CO)18(μ-SeH)]

Teresa M. Layer; Jack Lewis; Avelino Martín; Paul R. Raithby; Wing Tak Wong

doi:10.1016/0022-328X(93)83100-A

Synthesis of novel selenium-containing osmium carbonyl clusters: X-ray structures of [Os5(μ-H) (CO)15(μ3-SePh)] and [Os6(μ-H)(CO)18(μ-SeH)]

Teresa M. Layer, Jack Lewis, Avelino Martín, Paul R. Raithby, Wing Tak Wong

Research output: Journal article publication › Journal article › Academic research › peer-review

7 Citations (Scopus)

Abstract

The neutral osmium-selenido clusters [Os5(μ-H)(CO)15(μ3-SePh)] (2) and [Os6(μ3-H)(CO)18(μ3-SeH)] (5) have been isolated in good yield by reaction of PhSeCl with [Os5H(CO)15]-and [Os6H(CO)15]·-respectively. The structures of 2 and 5 have been established by single crystal X-ray analysis.

Original language	English
Journal	Journal of Organometallic Chemistry
Volume	444
Issue number	1-2
DOIs	https://doi.org/10.1016/0022-328X(93)83100-A
Publication status	Published - 9 Feb 1993
Externally published	Yes

ASJC Scopus subject areas

Biochemistry
Chemical Engineering (miscellaneous)
Inorganic Chemistry
Organic Chemistry
Physical and Theoretical Chemistry
Materials Science (miscellaneous)
Materials Chemistry

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10.1016/0022-328X(93)83100-A

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title = "Synthesis of novel selenium-containing osmium carbonyl clusters: X-ray structures of [Os5(μ-H) (CO)15(μ3-SePh)] and [Os6(μ-H)(CO)18(μ-SeH)]",

abstract = "The neutral osmium-selenido clusters [Os5(μ-H)(CO)15(μ3-SePh)] (2) and [Os6(μ3-H)(CO)18(μ3-SeH)] (5) have been isolated in good yield by reaction of PhSeCl with [Os5H(CO)15]-and [Os6H(CO)15]·-respectively. The structures of 2 and 5 have been established by single crystal X-ray analysis.",

author = "Layer, {Teresa M.} and Jack Lewis and Avelino Mart{\'i}n and Raithby, {Paul R.} and Wong, {Wing Tak}",

year = "1993",

month = feb,

day = "9",

doi = "10.1016/0022-328X(93)83100-A",

language = "English",

volume = "444",

journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

publisher = "Elsevier B.V.",

number = "1-2",

}

Synthesis of novel selenium-containing osmium carbonyl clusters: X-ray structures of [Os5(μ-H) (CO)15(μ3-SePh)] and [Os6(μ-H)(CO)18(μ-SeH)]. / Layer, Teresa M.; Lewis, Jack; Martín, Avelino et al.
In: Journal of Organometallic Chemistry, Vol. 444, No. 1-2, 09.02.1993.

Research output: Journal article publication › Journal article › Academic research › peer-review

TY - JOUR

T1 - Synthesis of novel selenium-containing osmium carbonyl clusters: X-ray structures of [Os5(μ-H) (CO)15(μ3-SePh)] and [Os6(μ-H)(CO)18(μ-SeH)]

AU - Layer, Teresa M.

AU - Lewis, Jack

AU - Martín, Avelino

AU - Raithby, Paul R.

AU - Wong, Wing Tak

PY - 1993/2/9

Y1 - 1993/2/9

N2 - The neutral osmium-selenido clusters [Os5(μ-H)(CO)15(μ3-SePh)] (2) and [Os6(μ3-H)(CO)18(μ3-SeH)] (5) have been isolated in good yield by reaction of PhSeCl with [Os5H(CO)15]-and [Os6H(CO)15]·-respectively. The structures of 2 and 5 have been established by single crystal X-ray analysis.

AB - The neutral osmium-selenido clusters [Os5(μ-H)(CO)15(μ3-SePh)] (2) and [Os6(μ3-H)(CO)18(μ3-SeH)] (5) have been isolated in good yield by reaction of PhSeCl with [Os5H(CO)15]-and [Os6H(CO)15]·-respectively. The structures of 2 and 5 have been established by single crystal X-ray analysis.

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U2 - 10.1016/0022-328X(93)83100-A

DO - 10.1016/0022-328X(93)83100-A

M3 - Journal article

SN - 0022-328X

VL - 444

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 1-2

ER -

Synthesis of novel selenium-containing osmium carbonyl clusters: X-ray structures of [Os5(μ-H) (CO)15(μ3-SePh)] and [Os6(μ-H)(CO)18(μ-SeH)]

Abstract

ASJC Scopus subject areas

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