Synthesis, characterization, X-ray structural analysis and study of oxidative properties of propyltriphenylphosphonium bromochromate

Shahriare Ghammamy, Monir Rahnama Baghy, Wing Tak Wong, Kheiroallah Mehrani, Saied Maleki

Research output: Journal article publicationJournal articleAcademic researchpeer-review

2 Citations (Scopus)

Abstract

The complex of propyltriphenylphosphonium bromochromate(VI), PrPh3P[CrO3Br] is easily synthesized in nearly quantitative yield using a direct reaction of chromium(VI) oxide and propyltriphenylphosphonium bromide. This compound is a versatile reagent for the efficient and selective oxidation of organic substrates, in particular for alcohols to their corresponding aldehydes or ketones, under mild conditions. This compound was characterized by IR, UV/Visible,13C-n.m.r. and1H-n.m.r. techniques. It crystallized in the monoclinic form and its crystal and molecular structure have been determined by X-ray crystallography.
Original languageEnglish
Pages (from-to)257-261
Number of pages5
JournalTransition Metal Chemistry
Volume32
Issue number2
DOIs
Publication statusPublished - 1 Mar 2007
Externally publishedYes

ASJC Scopus subject areas

  • Inorganic Chemistry
  • Metals and Alloys
  • Materials Chemistry

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