Synthesis, characterization, molecular and crystal structure of osmium-rhodium mixed-metal carbide cluster, [Os5Rh(μ5-C)(μ3-CO)(CO)13CP*]

Jasmine Po Kwan Lau; Wing Tak Wong

doi:10.1016/S1387-7003(03)00095-9

Synthesis, characterization, molecular and crystal structure of osmium-rhodium mixed-metal carbide cluster, [Os₅Rh(μ₅-C)(μ₃-CO)(CO)₁₃CP*]

Jasmine Po Kwan Lau
, Wing Tak Wong

Research output: Journal article publication › Journal article › Academic research › peer-review

8 Citations (Scopus)

Abstract

The hexanuclear osmium-rhodium carbonyl carbide cluster [Os5Rh(μ5-C)(μ3-CO)(CO)13Cp*] 3 has been synthesized in 66% yield by the ionic coupling reaction of [N(PPh3)2]2[Os5C (CO)14] 1 with [Rh2(CP*)2][BF4]22. An X-ray analysis on 3 showed a square based pyramidal metal skeleton with a μ3-CO bridging a RhOs2triangular face.

Original language	English
Pages (from-to)	733-736
Number of pages	4
Journal	Inorganic Chemistry Communications
Volume	6
Issue number	6
DOIs	https://doi.org/10.1016/S1387-7003(03)00095-9
Publication status	Published - 1 Jun 2003
Externally published	Yes

Keywords

Carbide
Osmium
Rhodium
X-ray crystallography

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

More information

10.1016/S1387-7003(03)00095-9

Cite this

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title = "Synthesis, characterization, molecular and crystal structure of osmium-rhodium mixed-metal carbide cluster, [Os5Rh(μ5-C)(μ3-CO)(CO)13CP*]",

abstract = "The hexanuclear osmium-rhodium carbonyl carbide cluster [Os5Rh(μ5-C)(μ3-CO)(CO)13Cp*] 3 has been synthesized in 66\% yield by the ionic coupling reaction of [N(PPh3)2]2[Os5C (CO)14] 1 with [Rh2(CP*)2][BF4]22. An X-ray analysis on 3 showed a square based pyramidal metal skeleton with a μ3-CO bridging a RhOs2triangular face.",

keywords = "Carbide, Osmium, Rhodium, X-ray crystallography",

author = "Lau, \{Jasmine Po Kwan\} and Wong, \{Wing Tak\}",

year = "2003",

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doi = "10.1016/S1387-7003(03)00095-9",

language = "English",

volume = "6",

pages = "733--736",

journal = "Inorganic Chemistry Communications",

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TY - JOUR

T1 - Synthesis, characterization, molecular and crystal structure of osmium-rhodium mixed-metal carbide cluster, [Os5Rh(μ5-C)(μ3-CO)(CO)13CP*]

AU - Lau, Jasmine Po Kwan

AU - Wong, Wing Tak

PY - 2003/6/1

Y1 - 2003/6/1

N2 - The hexanuclear osmium-rhodium carbonyl carbide cluster [Os5Rh(μ5-C)(μ3-CO)(CO)13Cp*] 3 has been synthesized in 66% yield by the ionic coupling reaction of [N(PPh3)2]2[Os5C (CO)14] 1 with [Rh2(CP*)2][BF4]22. An X-ray analysis on 3 showed a square based pyramidal metal skeleton with a μ3-CO bridging a RhOs2triangular face.

AB - The hexanuclear osmium-rhodium carbonyl carbide cluster [Os5Rh(μ5-C)(μ3-CO)(CO)13Cp*] 3 has been synthesized in 66% yield by the ionic coupling reaction of [N(PPh3)2]2[Os5C (CO)14] 1 with [Rh2(CP*)2][BF4]22. An X-ray analysis on 3 showed a square based pyramidal metal skeleton with a μ3-CO bridging a RhOs2triangular face.

KW - Carbide

KW - Osmium

KW - Rhodium

KW - X-ray crystallography

UR - https://www.scopus.com/pages/publications/0037730136

U2 - 10.1016/S1387-7003(03)00095-9

DO - 10.1016/S1387-7003(03)00095-9

M3 - Journal article

SN - 1387-7003

VL - 6

SP - 733

EP - 736

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

IS - 6

ER -