Abstract
The hexanuclear osmium-rhodium carbonyl carbide cluster [Os5Rh(μ5-C)(μ3-CO)(CO)13Cp*] 3 has been synthesized in 66% yield by the ionic coupling reaction of [N(PPh3)2]2[Os5C (CO)14] 1 with [Rh2(CP*)2][BF4]22. An X-ray analysis on 3 showed a square based pyramidal metal skeleton with a μ3-CO bridging a RhOs2triangular face.
Original language | English |
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Pages (from-to) | 733-736 |
Number of pages | 4 |
Journal | Inorganic Chemistry Communications |
Volume | 6 |
Issue number | 6 |
DOIs | |
Publication status | Published - 1 Jun 2003 |
Externally published | Yes |
Keywords
- Carbide
- Osmium
- Rhodium
- X-ray crystallography
ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Inorganic Chemistry
- Materials Chemistry