Synthesis, characterization, electrochemical properties and crystal and molecular structures of [HOs3(CO)10(O2CC5H4FeC5H5)] and[{Os3H(CO)10}2(O2CC5H4FeC5H4CO2)]

Siu Ming Lee, Kung Kai Cheung, Wing Tak Wong

Research output: Journal article publicationJournal articleAcademic researchpeer-review

32 Citations (Scopus)

Abstract

Two new air-stable triosmium clusters, [HOs3(CO)10(O2CC5H4FeC5H5)] (1) and [{Os3H(CO)10}2(O2CC5H4FeC5H4CO2)] (2), were obtained from the reaction of the labilized cluster [Os3(CO)10(CH3CN)2] and the corresponding ferrocenecarboxylic acid and were characterized by spectroscopic methods and single-crystal X-ray diffraction studies. The redox properties of both complexes were studied by cyclic voltammetry at ambient temperature; both exhibit a reversible electron transfer process.
Original languageEnglish
Pages (from-to)77-84
Number of pages8
JournalJournal of Organometallic Chemistry
Volume506
Issue number1-2
DOIs
Publication statusPublished - 1 Jan 1996

Keywords

  • Carbonyls
  • Cluster
  • Crystal structure
  • Ferrocenes
  • Iron
  • Osmium

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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