Synthesis, characterization, electrochemical properties and crystal and molecular structures of [HOs3(CO)10(O2CC5H4FeC5H5)] and[{Os3H(CO)10}2(O2CC5H4FeC5H4CO2)]

Siu Ming Lee; Kung Kai Cheung; Wing Tak Wong

doi:10.1016/0022-328X(95)05657-B

Synthesis, characterization, electrochemical properties and crystal and molecular structures of [HOs₃(CO)₁₀(O₂CC₅H₄FeC₅H5)] and[{Os₃H(CO)₁₀}₂(O₂CC₅H₄FeC₅H₄CO₂)]

Siu Ming Lee, Kung Kai Cheung, Wing Tak Wong

Research output: Journal article publication › Journal article › Academic research › peer-review

33 Citations (Scopus)

Abstract

Two new air-stable triosmium clusters, [HOs3(CO)10(O2CC5H4FeC5H5)] (1) and [{Os3H(CO)10}2(O2CC5H4FeC5H4CO2)] (2), were obtained from the reaction of the labilized cluster [Os3(CO)10(CH3CN)2] and the corresponding ferrocenecarboxylic acid and were characterized by spectroscopic methods and single-crystal X-ray diffraction studies. The redox properties of both complexes were studied by cyclic voltammetry at ambient temperature; both exhibit a reversible electron transfer process.

Original language	English
Pages (from-to)	77-84
Number of pages	8
Journal	Journal of Organometallic Chemistry
Volume	506
Issue number	1-2
DOIs	https://doi.org/10.1016/0022-328X(95)05657-B
Publication status	Published - 1 Jan 1996

Keywords

Carbonyls
Cluster
Crystal structure
Ferrocenes
Iron
Osmium

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
Materials Chemistry

More information

10.1016/0022-328X(95)05657-B

Cite this

@article{231122dca3f74f3199bf8c387f3880bd,

title = "Synthesis, characterization, electrochemical properties and crystal and molecular structures of [HOs3(CO)10(O2CC5H4FeC5H5)] and[{Os3H(CO)10}2(O2CC5H4FeC5H4CO2)]",

abstract = "Two new air-stable triosmium clusters, [HOs3(CO)10(O2CC5H4FeC5H5)] (1) and [{Os3H(CO)10}2(O2CC5H4FeC5H4CO2)] (2), were obtained from the reaction of the labilized cluster [Os3(CO)10(CH3CN)2] and the corresponding ferrocenecarboxylic acid and were characterized by spectroscopic methods and single-crystal X-ray diffraction studies. The redox properties of both complexes were studied by cyclic voltammetry at ambient temperature; both exhibit a reversible electron transfer process.",

keywords = "Carbonyls, Cluster, Crystal structure, Ferrocenes, Iron, Osmium",

author = "Lee, {Siu Ming} and Cheung, {Kung Kai} and Wong, {Wing Tak}",

year = "1996",

month = jan,

day = "1",

doi = "10.1016/0022-328X(95)05657-B",

language = "English",

volume = "506",

pages = "77--84",

journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

publisher = "Elsevier",

number = "1-2",

}

Synthesis, characterization, electrochemical properties and crystal and molecular structures of [HOs₃(CO)₁₀(O₂CC₅H₄FeC₅H5)] and[{Os₃H(CO)₁₀}₂(O₂CC₅H₄FeC₅H₄CO₂)]. / Lee, Siu Ming; Cheung, Kung Kai; Wong, Wing Tak.
In: Journal of Organometallic Chemistry, Vol. 506, No. 1-2, 01.01.1996, p. 77-84.

Research output: Journal article publication › Journal article › Academic research › peer-review

TY - JOUR

T1 - Synthesis, characterization, electrochemical properties and crystal and molecular structures of [HOs3(CO)10(O2CC5H4FeC5H5)] and[{Os3H(CO)10}2(O2CC5H4FeC5H4CO2)]

AU - Lee, Siu Ming

AU - Cheung, Kung Kai

AU - Wong, Wing Tak

PY - 1996/1/1

Y1 - 1996/1/1

N2 - Two new air-stable triosmium clusters, [HOs3(CO)10(O2CC5H4FeC5H5)] (1) and [{Os3H(CO)10}2(O2CC5H4FeC5H4CO2)] (2), were obtained from the reaction of the labilized cluster [Os3(CO)10(CH3CN)2] and the corresponding ferrocenecarboxylic acid and were characterized by spectroscopic methods and single-crystal X-ray diffraction studies. The redox properties of both complexes were studied by cyclic voltammetry at ambient temperature; both exhibit a reversible electron transfer process.

AB - Two new air-stable triosmium clusters, [HOs3(CO)10(O2CC5H4FeC5H5)] (1) and [{Os3H(CO)10}2(O2CC5H4FeC5H4CO2)] (2), were obtained from the reaction of the labilized cluster [Os3(CO)10(CH3CN)2] and the corresponding ferrocenecarboxylic acid and were characterized by spectroscopic methods and single-crystal X-ray diffraction studies. The redox properties of both complexes were studied by cyclic voltammetry at ambient temperature; both exhibit a reversible electron transfer process.

KW - Carbonyls

KW - Cluster

KW - Crystal structure

KW - Ferrocenes

KW - Iron

KW - Osmium

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U2 - 10.1016/0022-328X(95)05657-B

DO - 10.1016/0022-328X(95)05657-B

M3 - Journal article

SN - 0022-328X

VL - 506

SP - 77

EP - 84

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 1-2

ER -