Synthesis, characterization and molecular structure of a triruthenium carbonyl cluster containing both phenylimido and nitrosobenzene ligands

Kenneth Ka Hong Lee; Wing Tak Wong

doi:10.1039/dt9960003911

Synthesis, characterization and molecular structure of a triruthenium carbonyl cluster containing both phenylimido and nitrosobenzene ligands

Kenneth Ka Hong Lee, Wing Tak Wong

Research output: Journal article publication › Journal article › Academic research › peer-review

16 Citations (Scopus)

Abstract

The μ3-imido cluster [Ru3(CO)10(μ3-NPh)] reacted with an excess of nitrosobenzene in tetrahydrofuran to give [Ru3(CO)7(μ3-NPh)2(μ-η2-ONPh)2] which consists of a triruthenium metal core capped on two sides by two phenylimido ligands with two nitrosobenzene moieties bridging the two non-bonding Ru ⋯ Ru edges via the nitroso group.

Original language	English
Pages (from-to)	3911-3912
Number of pages	2
Journal	Journal of the Chemical Society - Dalton Transactions
Issue number	20
DOIs	https://doi.org/10.1039/dt9960003911
Publication status	Published - 21 Oct 1996
Externally published	Yes

ASJC Scopus subject areas

General Chemistry

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10.1039/dt9960003911

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title = "Synthesis, characterization and molecular structure of a triruthenium carbonyl cluster containing both phenylimido and nitrosobenzene ligands",

abstract = "The μ3-imido cluster [Ru3(CO)10(μ3-NPh)] reacted with an excess of nitrosobenzene in tetrahydrofuran to give [Ru3(CO)7(μ3-NPh)2(μ-η2-ONPh)2] which consists of a triruthenium metal core capped on two sides by two phenylimido ligands with two nitrosobenzene moieties bridging the two non-bonding Ru ⋯ Ru edges via the nitroso group.",

author = "Lee, {Kenneth Ka Hong} and Wong, {Wing Tak}",

year = "1996",

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doi = "10.1039/dt9960003911",

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journal = "Journal of the Chemical Society - Dalton Transactions",

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Synthesis, characterization and molecular structure of a triruthenium carbonyl cluster containing both phenylimido and nitrosobenzene ligands. / Lee, Kenneth Ka Hong; Wong, Wing Tak.
In: Journal of the Chemical Society - Dalton Transactions, No. 20, 21.10.1996, p. 3911-3912.

Research output: Journal article publication › Journal article › Academic research › peer-review

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AU - Wong, Wing Tak

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N2 - The μ3-imido cluster [Ru3(CO)10(μ3-NPh)] reacted with an excess of nitrosobenzene in tetrahydrofuran to give [Ru3(CO)7(μ3-NPh)2(μ-η2-ONPh)2] which consists of a triruthenium metal core capped on two sides by two phenylimido ligands with two nitrosobenzene moieties bridging the two non-bonding Ru ⋯ Ru edges via the nitroso group.

AB - The μ3-imido cluster [Ru3(CO)10(μ3-NPh)] reacted with an excess of nitrosobenzene in tetrahydrofuran to give [Ru3(CO)7(μ3-NPh)2(μ-η2-ONPh)2] which consists of a triruthenium metal core capped on two sides by two phenylimido ligands with two nitrosobenzene moieties bridging the two non-bonding Ru ⋯ Ru edges via the nitroso group.

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DO - 10.1039/dt9960003911

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JO - Journal of the Chemical Society - Dalton Transactions

JF - Journal of the Chemical Society - Dalton Transactions

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Synthesis, characterization and molecular structure of a triruthenium carbonyl cluster containing both phenylimido and nitrosobenzene ligands

Abstract

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