Synthesis, Characterization and Luminescent Properties of Copper(I) Halide Complexes Containing 1-(Diphenylphosphino)naphthalene

Qian Li; Li Liu; Xin Xin Zhong; Fa Bao Li; Abdullah M. Asiri; Khalid A. Alamry; Nian Yong Zhu; Wai Yeung Wong; Hai Mei Qin

doi:10.1007/s10904-017-0601-1

Synthesis, Characterization and Luminescent Properties of Copper(I) Halide Complexes Containing 1-(Diphenylphosphino)naphthalene

Qian Li, Li Liu, Xin Xin Zhong, Fa Bao Li, Abdullah M. Asiri, Khalid A. Alamry, Nian Yong Zhu, Wai Yeung Wong, Hai Mei Qin

Research output: Journal article publication › Journal article › Academic research › peer-review

6 Citations (Scopus)

Abstract

Abstract: A series of neutral luminescent tetranuclear and mononuclear copper(I) halide complexes, [Cu4I4(dpna)4] (1) and [CuX(dpna)2] dpna = 1-(diphenylphosphino)naphthalene, X = Br (2), Cl (3), were synthesized, and their molecular structures and photophysical properties were investigated. Complex 1 has a cubane-like structure with four Cu atoms pseudo-tetrahedral and four I atoms serving as μ3-bridges. The coordination geometry of the copper centers in 2–3 are trigonal-planar. In the solid state, complexes 1–3 display blue photoluminescence (λmax= 423–463 nm) at 298 K. The emission of the complexes originate from the (σ+X) transition. All three complexes displayed good thermal stability. Graphical Abstract: [Figure not available: see fulltext.]

Original language	English
Pages (from-to)	101-109
Number of pages	9
Journal	Journal of Inorganic and Organometallic Polymers and Materials
Volume	27
DOIs	https://doi.org/10.1007/s10904-017-0601-1
Publication status	Published - 1 Nov 2017

Keywords

Halide
Luminescence
Neutral Cu(I) complexes
Synthesis

ASJC Scopus subject areas

Polymers and Plastics
Materials Chemistry

More information

10.1007/s10904-017-0601-1

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title = "Synthesis, Characterization and Luminescent Properties of Copper(I) Halide Complexes Containing 1-(Diphenylphosphino)naphthalene",

abstract = "Abstract: A series of neutral luminescent tetranuclear and mononuclear copper(I) halide complexes, [Cu4I4(dpna)4] (1) and [CuX(dpna)2] dpna = 1-(diphenylphosphino)naphthalene, X = Br (2), Cl (3), were synthesized, and their molecular structures and photophysical properties were investigated. Complex 1 has a cubane-like structure with four Cu atoms pseudo-tetrahedral and four I atoms serving as μ3-bridges. The coordination geometry of the copper centers in 2–3 are trigonal-planar. In the solid state, complexes 1–3 display blue photoluminescence (λmax= 423–463 nm) at 298 K. The emission of the complexes originate from the (σ+X) transition. All three complexes displayed good thermal stability. Graphical Abstract: [Figure not available: see fulltext.]",

keywords = "Halide, Luminescence, Neutral Cu(I) complexes, Synthesis",

author = "Qian Li and Li Liu and Zhong, {Xin Xin} and Li, {Fa Bao} and Asiri, {Abdullah M.} and Alamry, {Khalid A.} and Zhu, {Nian Yong} and Wong, {Wai Yeung} and Qin, {Hai Mei}",

year = "2017",

month = nov,

day = "1",

doi = "10.1007/s10904-017-0601-1",

language = "English",

volume = "27",

pages = "101--109",

journal = "Journal of Inorganic and Organometallic Polymers and Materials",

issn = "1574-1443",

publisher = "Springer New York",

}

Synthesis, Characterization and Luminescent Properties of Copper(I) Halide Complexes Containing 1-(Diphenylphosphino)naphthalene. / Li, Qian; Liu, Li; Zhong, Xin Xin et al.
In: Journal of Inorganic and Organometallic Polymers and Materials, Vol. 27, 01.11.2017, p. 101-109.

Research output: Journal article publication › Journal article › Academic research › peer-review

TY - JOUR

T1 - Synthesis, Characterization and Luminescent Properties of Copper(I) Halide Complexes Containing 1-(Diphenylphosphino)naphthalene

AU - Li, Qian

AU - Liu, Li

AU - Zhong, Xin Xin

AU - Li, Fa Bao

AU - Asiri, Abdullah M.

AU - Alamry, Khalid A.

AU - Zhu, Nian Yong

AU - Wong, Wai Yeung

AU - Qin, Hai Mei

PY - 2017/11/1

Y1 - 2017/11/1

N2 - Abstract: A series of neutral luminescent tetranuclear and mononuclear copper(I) halide complexes, [Cu4I4(dpna)4] (1) and [CuX(dpna)2] dpna = 1-(diphenylphosphino)naphthalene, X = Br (2), Cl (3), were synthesized, and their molecular structures and photophysical properties were investigated. Complex 1 has a cubane-like structure with four Cu atoms pseudo-tetrahedral and four I atoms serving as μ3-bridges. The coordination geometry of the copper centers in 2–3 are trigonal-planar. In the solid state, complexes 1–3 display blue photoluminescence (λmax= 423–463 nm) at 298 K. The emission of the complexes originate from the (σ+X) transition. All three complexes displayed good thermal stability. Graphical Abstract: [Figure not available: see fulltext.]

AB - Abstract: A series of neutral luminescent tetranuclear and mononuclear copper(I) halide complexes, [Cu4I4(dpna)4] (1) and [CuX(dpna)2] dpna = 1-(diphenylphosphino)naphthalene, X = Br (2), Cl (3), were synthesized, and their molecular structures and photophysical properties were investigated. Complex 1 has a cubane-like structure with four Cu atoms pseudo-tetrahedral and four I atoms serving as μ3-bridges. The coordination geometry of the copper centers in 2–3 are trigonal-planar. In the solid state, complexes 1–3 display blue photoluminescence (λmax= 423–463 nm) at 298 K. The emission of the complexes originate from the (σ+X) transition. All three complexes displayed good thermal stability. Graphical Abstract: [Figure not available: see fulltext.]

KW - Halide

KW - Luminescence

KW - Neutral Cu(I) complexes

KW - Synthesis

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U2 - 10.1007/s10904-017-0601-1

DO - 10.1007/s10904-017-0601-1

M3 - Journal article

SN - 1574-1443

VL - 27

SP - 101

EP - 109

JO - Journal of Inorganic and Organometallic Polymers and Materials

JF - Journal of Inorganic and Organometallic Polymers and Materials

ER -

Synthesis, Characterization and Luminescent Properties of Copper(I) Halide Complexes Containing 1-(Diphenylphosphino)naphthalene

Abstract

Keywords

ASJC Scopus subject areas

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