Abstract
The pentaosmium carbide cluster [Os5C(CO)15] reacted with [Pd(PPh3)4] in CH2Cl2, giving a new hexanuclear osmium-palladium carbide cluster [Os5PdC(CO)12(μ-CO)2(PPh3)2] in moderate yield; treatment of [Os5C(CO)15] with [PdCl2(PPh3)2] in refluxing chloroform gave [Os5PdC(CO)15-(μ-Cl)2(PPh3)] in low yield, which consists of a novel metal core geometry with a Pd-C (carbide) bond.
| Original language | English |
|---|---|
| Pages (from-to) | 2887-2888 |
| Number of pages | 2 |
| Journal | Journal of the Chemical Society - Dalton Transactions |
| Issue number | 13 |
| DOIs | |
| Publication status | Published - 7 Jul 1996 |
| Externally published | Yes |
ASJC Scopus subject areas
- General Chemistry
Fingerprint
Dive into the research topics of 'Synthesis, characterisation, molecular and crystal structures of two novel osmium-palladium carbide carbonyl clusters'. Together they form a unique fingerprint.Cite this
- APA
- Author
- BIBTEX
- Harvard
- Standard
- RIS
- Vancouver