Synthesis, characterisation, molecular and crystal structures of two novel osmium-palladium carbide carbonyl clusters

Janesse Wing Sze Hui, Wing Tak Wong

Research output: Journal article publicationJournal articleAcademic researchpeer-review

18 Citations (Scopus)

Abstract

The pentaosmium carbide cluster [Os5C(CO)15] reacted with [Pd(PPh3)4] in CH2Cl2, giving a new hexanuclear osmium-palladium carbide cluster [Os5PdC(CO)12(μ-CO)2(PPh3)2] in moderate yield; treatment of [Os5C(CO)15] with [PdCl2(PPh3)2] in refluxing chloroform gave [Os5PdC(CO)15-(μ-Cl)2(PPh3)] in low yield, which consists of a novel metal core geometry with a Pd-C (carbide) bond.
Original languageEnglish
Pages (from-to)2887-2888
Number of pages2
JournalJournal of the Chemical Society - Dalton Transactions
Issue number13
DOIs
Publication statusPublished - 7 Jul 1996
Externally publishedYes

ASJC Scopus subject areas

  • Chemistry(all)

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