Abstract
The pentaosmium carbide cluster [Os5C(CO)15] reacted with [Pd(PPh3)4] in CH2Cl2, giving a new hexanuclear osmium-palladium carbide cluster [Os5PdC(CO)12(μ-CO)2(PPh3)2] in moderate yield; treatment of [Os5C(CO)15] with [PdCl2(PPh3)2] in refluxing chloroform gave [Os5PdC(CO)15-(μ-Cl)2(PPh3)] in low yield, which consists of a novel metal core geometry with a Pd-C (carbide) bond.
Original language | English |
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Pages (from-to) | 2887-2888 |
Number of pages | 2 |
Journal | Journal of the Chemical Society - Dalton Transactions |
Issue number | 13 |
DOIs | |
Publication status | Published - 7 Jul 1996 |
Externally published | Yes |
ASJC Scopus subject areas
- General Chemistry