Synthesis, characterisation, molecular and crystal structures of two novel osmium-palladium carbide carbonyl clusters

Janesse Wing Sze Hui; Wing Tak Wong

doi:10.1039/DT9960002887

Synthesis, characterisation, molecular and crystal structures of two novel osmium-palladium carbide carbonyl clusters

Janesse Wing Sze Hui, Wing Tak Wong

Research output: Journal article publication › Journal article › Academic research › peer-review

19 Citations (Scopus)

Abstract

The pentaosmium carbide cluster [Os5C(CO)15] reacted with [Pd(PPh3)4] in CH2Cl2, giving a new hexanuclear osmium-palladium carbide cluster [Os5PdC(CO)12(μ-CO)2(PPh3)2] in moderate yield; treatment of [Os5C(CO)15] with [PdCl2(PPh3)2] in refluxing chloroform gave [Os5PdC(CO)15-(μ-Cl)2(PPh3)] in low yield, which consists of a novel metal core geometry with a Pd-C (carbide) bond.

Original language	English
Pages (from-to)	2887-2888
Number of pages	2
Journal	Journal of the Chemical Society - Dalton Transactions
Issue number	13
DOIs	https://doi.org/10.1039/DT9960002887
Publication status	Published - 7 Jul 1996
Externally published	Yes

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Chemistry(all)

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10.1039/DT9960002887

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title = "Synthesis, characterisation, molecular and crystal structures of two novel osmium-palladium carbide carbonyl clusters",

abstract = "The pentaosmium carbide cluster [Os5C(CO)15] reacted with [Pd(PPh3)4] in CH2Cl2, giving a new hexanuclear osmium-palladium carbide cluster [Os5PdC(CO)12(μ-CO)2(PPh3)2] in moderate yield; treatment of [Os5C(CO)15] with [PdCl2(PPh3)2] in refluxing chloroform gave [Os5PdC(CO)15-(μ-Cl)2(PPh3)] in low yield, which consists of a novel metal core geometry with a Pd-C (carbide) bond.",

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year = "1996",

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AU - Hui, Janesse Wing Sze

AU - Wong, Wing Tak

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N2 - The pentaosmium carbide cluster [Os5C(CO)15] reacted with [Pd(PPh3)4] in CH2Cl2, giving a new hexanuclear osmium-palladium carbide cluster [Os5PdC(CO)12(μ-CO)2(PPh3)2] in moderate yield; treatment of [Os5C(CO)15] with [PdCl2(PPh3)2] in refluxing chloroform gave [Os5PdC(CO)15-(μ-Cl)2(PPh3)] in low yield, which consists of a novel metal core geometry with a Pd-C (carbide) bond.

AB - The pentaosmium carbide cluster [Os5C(CO)15] reacted with [Pd(PPh3)4] in CH2Cl2, giving a new hexanuclear osmium-palladium carbide cluster [Os5PdC(CO)12(μ-CO)2(PPh3)2] in moderate yield; treatment of [Os5C(CO)15] with [PdCl2(PPh3)2] in refluxing chloroform gave [Os5PdC(CO)15-(μ-Cl)2(PPh3)] in low yield, which consists of a novel metal core geometry with a Pd-C (carbide) bond.

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DO - 10.1039/DT9960002887

M3 - Journal article

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JO - Journal of the Chemical Society. Dalton Transactions

JF - Journal of the Chemical Society. Dalton Transactions

IS - 13

ER -

Synthesis, characterisation, molecular and crystal structures of two novel osmium-palladium carbide carbonyl clusters

Abstract

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