Synthesis, characterisation and molecular structure of [Ru5C(CO)15(HgCF3)(CF3CO2)]

Brian F.G. Johnson; Jack Lewis; Paul R. Raithby; Vijay P. Saharan; Wing Tak Wong

doi:10.1016/0022-328X(92)83362-L

Synthesis, characterisation and molecular structure of [Ru₅C(CO)₁₅(HgCF₃)(CF₃CO₂)]

Brian F.G. Johnson, Jack Lewis, Paul R. Raithby, Vijay P. Saharan, Wing Tak Wong

Research output: Journal article publication › Journal article › Academic research › peer-review

3 Citations (Scopus)

Abstract

Treatment of [Ru5C(CO)15] with one equivalent of [Hg(CF3)(CF3CO2)], in CH2Cl2, at room temperature affords the new cluster [RU5C(CO)15(HgCF3)(CF3CO2)] (1) in quantitative yield. A single crystal X-ray structural study of 1 shows that it contains a bridged-butterfly Ru5metal core with the HgCF3fragment bridging at the hinge position and the trifluoroacetate coordinated to the bridging ruthenium atom through one oxygen atom.

Original language	English
Journal	Journal of Organometallic Chemistry
Volume	434
Issue number	1
DOIs	https://doi.org/10.1016/0022-328X(92)83362-L
Publication status	Published - 4 Aug 1992
Externally published	Yes

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/0022-328X(92)83362-L

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title = "Synthesis, characterisation and molecular structure of [Ru5C(CO)15(HgCF3)(CF3CO2)]",

abstract = "Treatment of [Ru5C(CO)15] with one equivalent of [Hg(CF3)(CF3CO2)], in CH2Cl2, at room temperature affords the new cluster [RU5C(CO)15(HgCF3)(CF3CO2)] (1) in quantitative yield. A single crystal X-ray structural study of 1 shows that it contains a bridged-butterfly Ru5metal core with the HgCF3fragment bridging at the hinge position and the trifluoroacetate coordinated to the bridging ruthenium atom through one oxygen atom.",

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AU - Johnson, Brian F.G.

AU - Lewis, Jack

AU - Raithby, Paul R.

AU - Saharan, Vijay P.

AU - Wong, Wing Tak

PY - 1992/8/4

Y1 - 1992/8/4

N2 - Treatment of [Ru5C(CO)15] with one equivalent of [Hg(CF3)(CF3CO2)], in CH2Cl2, at room temperature affords the new cluster [RU5C(CO)15(HgCF3)(CF3CO2)] (1) in quantitative yield. A single crystal X-ray structural study of 1 shows that it contains a bridged-butterfly Ru5metal core with the HgCF3fragment bridging at the hinge position and the trifluoroacetate coordinated to the bridging ruthenium atom through one oxygen atom.

AB - Treatment of [Ru5C(CO)15] with one equivalent of [Hg(CF3)(CF3CO2)], in CH2Cl2, at room temperature affords the new cluster [RU5C(CO)15(HgCF3)(CF3CO2)] (1) in quantitative yield. A single crystal X-ray structural study of 1 shows that it contains a bridged-butterfly Ru5metal core with the HgCF3fragment bridging at the hinge position and the trifluoroacetate coordinated to the bridging ruthenium atom through one oxygen atom.

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U2 - 10.1016/0022-328X(92)83362-L

DO - 10.1016/0022-328X(92)83362-L

M3 - Journal article

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VL - 434

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 1

ER -

Synthesis, characterisation and molecular structure of [Ru₅C(CO)₁₅(HgCF₃)(CF₃CO₂)]

Abstract

ASJC Scopus subject areas

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