Synthesis and X-ray structure of the osmium carbonyl anion [HOs3(CO)10· O2C · Os6(CO)20]-

Brian F.G. Johnson; Jack Lewis; Paul R. Raithby; Wing Tak Wong

doi:10.1016/0022-328X(91)86240-Q

Synthesis and X-ray structure of the osmium carbonyl anion [HOs₃(CO)₁₀· O₂C · Os₆(CO)₂₀]^-

Brian F.G. Johnson
, Jack Lewis
, Paul R. Raithby
, Wing Tak Wong

Research output: Journal article publication › Journal article › Academic research › peer-review

17 Citations (Scopus)

Abstract

The reaction of [HOs3(CO)11]-11with [Os3(CO)10(MeCN)2] in acetone gives the green-blue anion [HOs3(CO)10·O2C·Os6(CO)20]-(1) amongst several other products; this anion has been structurally characterised by a single crystal X-ray study of its Bu4P+salt.

Original language	English
Journal	Journal of Organometallic Chemistry
Volume	401
Issue number	3
DOIs	https://doi.org/10.1016/0022-328X(91)86240-Q
Publication status	Published - 15 Jan 1991
Externally published	Yes

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/0022-328X(91)86240-Q

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title = "Synthesis and X-ray structure of the osmium carbonyl anion [HOs3(CO)10· O2C · Os6(CO)20]-",

abstract = "The reaction of [HOs3(CO)11]-11with [Os3(CO)10(MeCN)2] in acetone gives the green-blue anion [HOs3(CO)10·O2C·Os6(CO)20]-(1) amongst several other products; this anion has been structurally characterised by a single crystal X-ray study of its Bu4P+salt.",

author = "Johnson, \{Brian F.G.\} and Jack Lewis and Raithby, \{Paul R.\} and Wong, \{Wing Tak\}",

year = "1991",

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T1 - Synthesis and X-ray structure of the osmium carbonyl anion [HOs3(CO)10· O2C · Os6(CO)20]-

AU - Johnson, Brian F.G.

AU - Lewis, Jack

AU - Raithby, Paul R.

AU - Wong, Wing Tak

PY - 1991/1/15

Y1 - 1991/1/15

N2 - The reaction of [HOs3(CO)11]-11with [Os3(CO)10(MeCN)2] in acetone gives the green-blue anion [HOs3(CO)10·O2C·Os6(CO)20]-(1) amongst several other products; this anion has been structurally characterised by a single crystal X-ray study of its Bu4P+salt.

AB - The reaction of [HOs3(CO)11]-11with [Os3(CO)10(MeCN)2] in acetone gives the green-blue anion [HOs3(CO)10·O2C·Os6(CO)20]-(1) amongst several other products; this anion has been structurally characterised by a single crystal X-ray study of its Bu4P+salt.

UR - https://www.scopus.com/pages/publications/4244212826

U2 - 10.1016/0022-328X(91)86240-Q

DO - 10.1016/0022-328X(91)86240-Q

M3 - Journal article

SN - 0022-328X

VL - 401

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 3

ER -

Synthesis and X-ray structure of the osmium carbonyl anion [HOs₃(CO)₁₀· O₂C · Os₆(CO)₂₀]^-

Abstract

ASJC Scopus subject areas

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