Synthesis and X-ray crystal structure of cis-(CO)4Cr[(Me3SiN)C(Ph)(NHPPh2)]

Wong Wai-Kwok, Jiang Tao, Daniel W J Kwong, Wing Tak Wong

Research output: Journal article publicationJournal articleAcademic researchpeer-review

2 Citations (Scopus)

Abstract

The interaction of (Ph2PN)C(Ph)[N(SiMe3)2] with one equivalent of C7H8Cr(CO)4in diethyl ether gave cis-(CO)4Cr[(Me3SiN)C(Ph)(NHPPh2)] in good yield. The compound has been fully characterized by analytical, spectroscopic and X-ray diffraction methods. The NH proton of the bidentate iminophosphine ligand undergoes facile deuterium exchange with D2O at ambient temperature. A 1,3-silyl shift mechanism has been proposed for the formation of the product.
Original languageEnglish
Pages (from-to)1695-1697
Number of pages3
JournalPolyhedron
Volume14
Issue number12
DOIs
Publication statusPublished - 1 Jan 1995
Externally publishedYes

ASJC Scopus subject areas

  • Inorganic Chemistry
  • Physical and Theoretical Chemistry
  • Materials Chemistry

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