Synthesis and structure of an air-stable hypervalent organobismuth (III) perfluorooctanesulfonate and its use as high-efficiency catalyst for Mannich-type reactions in water

Xiaowen Zhang; Shuangfeng Yin; Renhua Qiu; Jun Xia; Weili Dai; Zhenying Yu; Chak Tong Au; Wai Yeung Wong

doi:10.1016/j.jorganchem.2009.07.018

Synthesis and structure of an air-stable hypervalent organobismuth (III) perfluorooctanesulfonate and its use as high-efficiency catalyst for Mannich-type reactions in water

Xiaowen Zhang
, Shuangfeng Yin
, Renhua Qiu
, Jun Xia
, Weili Dai
, Zhenying Yu
, Chak Tong Au
, Wai Yeung Wong

Research output: Journal article publication › Journal article › Academic research › peer-review

57 Citations (Scopus)

Abstract

An air-stable hypervalent organobismuth (III) perfluorooctanesulfonate was synthesized and characterized by spectroscopic and X-ray crystallographic techniques, and found to exhibit high catalytic efficiency towards one-pot Mannich-type reaction of ketones with aromatic aldehydes and aromatic amines in water. This catalyst also shows good recyclability and reusability. This catalytic system would provide a simple, efficient and 'green' avenue towards the synthesis of β-amino ketones.

Original language	English
Pages (from-to)	3559-3564
Number of pages	6
Journal	Journal of Organometallic Chemistry
Volume	694
Issue number	22
DOIs	https://doi.org/10.1016/j.jorganchem.2009.07.018
Publication status	Published - 15 Oct 2009
Externally published	Yes

Keywords

Crystal structure
Mannich
Organobismuth
Perfluorooctanesulfonate
Three-component reaction

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
Materials Chemistry

More information

10.1016/j.jorganchem.2009.07.018

Cite this

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title = "Synthesis and structure of an air-stable hypervalent organobismuth (III) perfluorooctanesulfonate and its use as high-efficiency catalyst for Mannich-type reactions in water",

abstract = "An air-stable hypervalent organobismuth (III) perfluorooctanesulfonate was synthesized and characterized by spectroscopic and X-ray crystallographic techniques, and found to exhibit high catalytic efficiency towards one-pot Mannich-type reaction of ketones with aromatic aldehydes and aromatic amines in water. This catalyst also shows good recyclability and reusability. This catalytic system would provide a simple, efficient and 'green' avenue towards the synthesis of β-amino ketones.",

keywords = "Crystal structure, Mannich, Organobismuth, Perfluorooctanesulfonate, Three-component reaction",

author = "Xiaowen Zhang and Shuangfeng Yin and Renhua Qiu and Jun Xia and Weili Dai and Zhenying Yu and Au, \{Chak Tong\} and Wong, \{Wai Yeung\}",

year = "2009",

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day = "15",

doi = "10.1016/j.jorganchem.2009.07.018",

language = "English",

volume = "694",

pages = "3559--3564",

journal = "Journal of Organometallic Chemistry",

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publisher = "Elsevier B.V.",

number = "22",

}

Synthesis and structure of an air-stable hypervalent organobismuth (III) perfluorooctanesulfonate and its use as high-efficiency catalyst for Mannich-type reactions in water. / Zhang, Xiaowen; Yin, Shuangfeng; Qiu, Renhua et al.
In: Journal of Organometallic Chemistry, Vol. 694, No. 22, 15.10.2009, p. 3559-3564.

Research output: Journal article publication › Journal article › Academic research › peer-review

TY - JOUR

T1 - Synthesis and structure of an air-stable hypervalent organobismuth (III) perfluorooctanesulfonate and its use as high-efficiency catalyst for Mannich-type reactions in water

AU - Zhang, Xiaowen

AU - Yin, Shuangfeng

AU - Qiu, Renhua

AU - Xia, Jun

AU - Dai, Weili

AU - Yu, Zhenying

AU - Au, Chak Tong

AU - Wong, Wai Yeung

PY - 2009/10/15

Y1 - 2009/10/15

N2 - An air-stable hypervalent organobismuth (III) perfluorooctanesulfonate was synthesized and characterized by spectroscopic and X-ray crystallographic techniques, and found to exhibit high catalytic efficiency towards one-pot Mannich-type reaction of ketones with aromatic aldehydes and aromatic amines in water. This catalyst also shows good recyclability and reusability. This catalytic system would provide a simple, efficient and 'green' avenue towards the synthesis of β-amino ketones.

AB - An air-stable hypervalent organobismuth (III) perfluorooctanesulfonate was synthesized and characterized by spectroscopic and X-ray crystallographic techniques, and found to exhibit high catalytic efficiency towards one-pot Mannich-type reaction of ketones with aromatic aldehydes and aromatic amines in water. This catalyst also shows good recyclability and reusability. This catalytic system would provide a simple, efficient and 'green' avenue towards the synthesis of β-amino ketones.

KW - Crystal structure

KW - Mannich

KW - Organobismuth

KW - Perfluorooctanesulfonate

KW - Three-component reaction

UR - https://www.scopus.com/pages/publications/69949085945

U2 - 10.1016/j.jorganchem.2009.07.018

DO - 10.1016/j.jorganchem.2009.07.018

M3 - Journal article

SN - 0022-328X

VL - 694

SP - 3559

EP - 3564

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 22

ER -

Synthesis and structure of an air-stable hypervalent organobismuth (III) perfluorooctanesulfonate and its use as high-efficiency catalyst for Mannich-type reactions in water

Abstract

Keywords

ASJC Scopus subject areas

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