Synthesis and structural characterization of some arylamidinium diphenylphosphinates: Formation of one-, two- and three-dimensional networks by charge-assisted hydrogen bonds

Jianping Guo, Wai Kwok Wong, Wai Yeung Wong

Research output: Journal article publicationJournal articleAcademic researchpeer-review

13 Citations (Scopus)

Abstract

In the presence of air, the interaction of AgSO3CF3with phosphorus-nitrogen π-electron-rich compounds ArC(NPPh2)[N(SiMe3)2] (Ar = phenyl, p-tolyl, 4-pyridyl, 3-pyridyl and 2-pyridyl) and 1,4-C6H4{C(NPPh2)[N(SiMe3)2]}2in acetonitrile led to the formation of metallic silver and the oxidative cleavage product {[ArC(NH2)2](Ph2PO2)}n(Ar = phenyl, 1; p-tolyl, 2; 4-pyridyl, 3; 3-pyridyl, 4; 2-pyridyl, 5) and [{1,4-C6H4[C(NH2)2]2}(Ph2PO2)2]n(6), respectively. Structural analyses of compounds 1-6 revealed that these ionic salts are held together by charge-assisted hydrogen bonds forming 1D, 2D and 3D polymeric networks.
Original languageEnglish
Pages (from-to)927-939
Number of pages13
JournalPolyhedron
Volume24
Issue number8
DOIs
Publication statusPublished - 2 Jun 2005
Externally publishedYes

Keywords

  • Amidinium diphenylphosphinate
  • Charge-assisted hydrogen bond
  • Crystal structures
  • Electrostatic force
  • Oxidative cleavage

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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