Synthesis and structural characterisation of tetraruthenium μ4-nitrene clusters containing tolylacetylene (HC2Tol). Molecular structures of [Ru4(CO)9(μ-CO)2(μ4-NH)(μ4-η2-HC2Tol)] and [Ru4(CO)9(μ-CO)2{μ4-NC(O)OMe}...

Emmie Ngai Man Ho; Wing Tak Wong

doi:10.1039/a708168e

Synthesis and structural characterisation of tetraruthenium μ₄-nitrene clusters containing tolylacetylene (HC₂Tol). Molecular structures of [Ru₄(CO)₉(μ-CO)₂(μ₄-NH)(μ₄-η²-HC₂Tol)] and [Ru₄(CO)₉(μ-CO)₂{μ₄-NC(O)OMe}...

Emmie Ngai Man Ho
, Wing Tak Wong

Research output: Journal article publication › Journal article › Academic research › peer-review

18 Citations (Scopus)

Abstract

Full title: Synthesis and structural characterisation of tetraruthenium μ4-nitrene clusters containing tolylacetylene (HC2Tol). Molecular structures of [Ru4(CO)9(μ-CO)2(μ4-NH)(μ4-η2-HC2Tol)] and [Ru4(CO)9(μ-CO)2{μ4-NC(O)OMe}(μ4-η2-HC2Tol)] Two structurally characterized tetraruthenium carbonyl clusters, [Ru4(CO)9(μ-CO)2(μ4-NH)(μ4-η2-HC2Tol)] 1 and [Ru4(CO)9(μ-CO)2{μ4-NC(O)OMe}(μ4-η2-HC2Tol)] 2, have been isolated from the reaction between [Ru3(CO)9(μ3-CO)(μ3-NOMe)] and tolylacetylene (HC2Tol) in refluxing n-octane.

Original language	English
Pages (from-to)	513-514
Number of pages	2
Journal	Journal of the Chemical Society - Dalton Transactions
Issue number	4
DOIs	https://doi.org/10.1039/a708168e
Publication status	Published - 1 Jan 1998
Externally published	Yes

ASJC Scopus subject areas

General Chemistry

More information

10.1039/a708168e

Fingerprint

Dive into the research topics of 'Synthesis and structural characterisation of tetraruthenium μ₄-nitrene clusters containing tolylacetylene (HC₂Tol). Molecular structures of [Ru₄(CO)₉(μ-CO)₂(μ₄-NH)(μ₄-η²-HC₂Tol)] and [Ru₄(CO)₉(μ-CO)₂{μ₄-NC(O)OMe}...'. Together they form a unique fingerprint.

Cite this

@article{084f43b0a22848e0821265990f9fb66d,

title = "Synthesis and structural characterisation of tetraruthenium μ4-nitrene clusters containing tolylacetylene (HC2Tol). Molecular structures of [Ru4(CO)9(μ-CO)2(μ4-NH)(μ4-η2-HC2Tol)] and [Ru4(CO)9(μ-CO)2\{μ4-NC(O)OMe\}...",

abstract = "Full title: Synthesis and structural characterisation of tetraruthenium μ4-nitrene clusters containing tolylacetylene (HC2Tol). Molecular structures of [Ru4(CO)9(μ-CO)2(μ4-NH)(μ4-η2-HC2Tol)] and [Ru4(CO)9(μ-CO)2\{μ4-NC(O)OMe\}(μ4-η2-HC2Tol)] Two structurally characterized tetraruthenium carbonyl clusters, [Ru4(CO)9(μ-CO)2(μ4-NH)(μ4-η2-HC2Tol)] 1 and [Ru4(CO)9(μ-CO)2\{μ4-NC(O)OMe\}(μ4-η2-HC2Tol)] 2, have been isolated from the reaction between [Ru3(CO)9(μ3-CO)(μ3-NOMe)] and tolylacetylene (HC2Tol) in refluxing n-octane.",

author = "Ho, \{Emmie Ngai Man\} and Wong, \{Wing Tak\}",

year = "1998",

month = jan,

day = "1",

doi = "10.1039/a708168e",

language = "English",

pages = "513--514",

journal = "Journal of the Chemical Society - Dalton Transactions",

issn = "0300-9246",

publisher = "Royal Society of Chemistry",

number = "4",

}

Synthesis and structural characterisation of tetraruthenium μ₄-nitrene clusters containing tolylacetylene (HC₂Tol). Molecular structures of [Ru₄(CO)₉(μ-CO)₂(μ₄-NH)(μ₄-η²-HC₂Tol)] and [Ru₄(CO)₉(μ-CO)₂{μ₄-NC(O)OMe}... / Ho, Emmie Ngai Man; Wong, Wing Tak.
In: Journal of the Chemical Society - Dalton Transactions, No. 4, 01.01.1998, p. 513-514.

Research output: Journal article publication › Journal article › Academic research › peer-review

TY - JOUR

T1 - Synthesis and structural characterisation of tetraruthenium μ4-nitrene clusters containing tolylacetylene (HC2Tol). Molecular structures of [Ru4(CO)9(μ-CO)2(μ4-NH)(μ4-η2-HC2Tol)] and [Ru4(CO)9(μ-CO)2{μ4-NC(O)OMe}...

AU - Ho, Emmie Ngai Man

AU - Wong, Wing Tak

PY - 1998/1/1

Y1 - 1998/1/1

N2 - Full title: Synthesis and structural characterisation of tetraruthenium μ4-nitrene clusters containing tolylacetylene (HC2Tol). Molecular structures of [Ru4(CO)9(μ-CO)2(μ4-NH)(μ4-η2-HC2Tol)] and [Ru4(CO)9(μ-CO)2{μ4-NC(O)OMe}(μ4-η2-HC2Tol)] Two structurally characterized tetraruthenium carbonyl clusters, [Ru4(CO)9(μ-CO)2(μ4-NH)(μ4-η2-HC2Tol)] 1 and [Ru4(CO)9(μ-CO)2{μ4-NC(O)OMe}(μ4-η2-HC2Tol)] 2, have been isolated from the reaction between [Ru3(CO)9(μ3-CO)(μ3-NOMe)] and tolylacetylene (HC2Tol) in refluxing n-octane.

AB - Full title: Synthesis and structural characterisation of tetraruthenium μ4-nitrene clusters containing tolylacetylene (HC2Tol). Molecular structures of [Ru4(CO)9(μ-CO)2(μ4-NH)(μ4-η2-HC2Tol)] and [Ru4(CO)9(μ-CO)2{μ4-NC(O)OMe}(μ4-η2-HC2Tol)] Two structurally characterized tetraruthenium carbonyl clusters, [Ru4(CO)9(μ-CO)2(μ4-NH)(μ4-η2-HC2Tol)] 1 and [Ru4(CO)9(μ-CO)2{μ4-NC(O)OMe}(μ4-η2-HC2Tol)] 2, have been isolated from the reaction between [Ru3(CO)9(μ3-CO)(μ3-NOMe)] and tolylacetylene (HC2Tol) in refluxing n-octane.

UR - https://www.scopus.com/pages/publications/36849086555

U2 - 10.1039/a708168e

DO - 10.1039/a708168e

M3 - Journal article

SN - 0300-9246

SP - 513

EP - 514

JO - Journal of the Chemical Society - Dalton Transactions

JF - Journal of the Chemical Society - Dalton Transactions

IS - 4

ER -