Synthesis and structural characterisation of tetraruthenium μ4-nitrene clusters containing tolylacetylene (HC2Tol). Molecular structures of [Ru4(CO)9(μ-CO)24-NH)(μ42-HC2Tol)] and [Ru4(CO)9(μ-CO)24-NC(O)OMe}...

Emmie Ngai Man Ho, Wing Tak Wong

Research output: Journal article publicationJournal articleAcademic researchpeer-review

18 Citations (Scopus)

Abstract

Full title: Synthesis and structural characterisation of tetraruthenium μ4-nitrene clusters containing tolylacetylene (HC2Tol). Molecular structures of [Ru4(CO)9(μ-CO)2(μ4-NH)(μ4-η2-HC2Tol)] and [Ru4(CO)9(μ-CO)2{μ4-NC(O)OMe}(μ4-η2-HC2Tol)] Two structurally characterized tetraruthenium carbonyl clusters, [Ru4(CO)9(μ-CO)2(μ4-NH)(μ4-η2-HC2Tol)] 1 and [Ru4(CO)9(μ-CO)2{μ4-NC(O)OMe}(μ4-η2-HC2Tol)] 2, have been isolated from the reaction between [Ru3(CO)9(μ3-CO)(μ3-NOMe)] and tolylacetylene (HC2Tol) in refluxing n-octane.
Original languageEnglish
Pages (from-to)513-514
Number of pages2
JournalJournal of the Chemical Society - Dalton Transactions
Issue number4
DOIs
Publication statusPublished - 1 Jan 1998
Externally publishedYes

ASJC Scopus subject areas

  • Chemistry(all)

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