Synthesis and photochromic studies of η6-mesitylene ruthenium(ii) complexes bearing N-heterocyclic carbene ligands with the dithienylethene moiety

Gongping Duan; Wing Tak Wong; Vivian Wing Wah Yam

doi:10.1039/c1nj20161a

Synthesis and photochromic studies of η⁶-mesitylene ruthenium(ii) complexes bearing N-heterocyclic carbene ligands with the dithienylethene moiety

Gongping Duan
, Wing Tak Wong
, Vivian Wing Wah Yam

Research output: Journal article publication › Journal article › Academic research › peer-review

24 Citations (Scopus)

Abstract

A series of half-sandwich type ruthenium(ii) complexes, [(η6-mesitylene)Ru(NHC-L)Cl]PF6 (NHC = N-heterocyclic carbene, L = azole and imine ligand), containing the dithienylethene moiety has been synthesized and characterized by 1H NMR, X-ray crystallography and electronic absorption spectroscopy. These complexes show photochromic properties upon UV photo-irradiation to generate the closed forms of the dithienylethene moiety.

Original language	English
Pages (from-to)	2267-2278
Number of pages	12
Journal	New Journal of Chemistry
Volume	35
Issue number	10
DOIs	https://doi.org/10.1039/c1nj20161a
Publication status	Published - 1 Oct 2011
Externally published	Yes

ASJC Scopus subject areas

Catalysis
General Chemistry
Materials Chemistry

More information

10.1039/c1nj20161a

Cite this

@article{fc31b0a228594be09aaa9f088c81f5ff,

title = "Synthesis and photochromic studies of η6-mesitylene ruthenium(ii) complexes bearing N-heterocyclic carbene ligands with the dithienylethene moiety",

abstract = "A series of half-sandwich type ruthenium(ii) complexes, [(η6-mesitylene)Ru(NHC-L)Cl]PF6 (NHC = N-heterocyclic carbene, L = azole and imine ligand), containing the dithienylethene moiety has been synthesized and characterized by 1H NMR, X-ray crystallography and electronic absorption spectroscopy. These complexes show photochromic properties upon UV photo-irradiation to generate the closed forms of the dithienylethene moiety.",

author = "Gongping Duan and Wong, \{Wing Tak\} and Yam, \{Vivian Wing Wah\}",

year = "2011",

month = oct,

day = "1",

doi = "10.1039/c1nj20161a",

language = "English",

volume = "35",

pages = "2267--2278",

journal = "New Journal of Chemistry",

issn = "1144-0546",

publisher = "Royal Society of Chemistry",

number = "10",

}

Synthesis and photochromic studies of η⁶-mesitylene ruthenium(ii) complexes bearing N-heterocyclic carbene ligands with the dithienylethene moiety. / Duan, Gongping; Wong, Wing Tak; Yam, Vivian Wing Wah.
In: New Journal of Chemistry, Vol. 35, No. 10, 01.10.2011, p. 2267-2278.

Research output: Journal article publication › Journal article › Academic research › peer-review

TY - JOUR

T1 - Synthesis and photochromic studies of η6-mesitylene ruthenium(ii) complexes bearing N-heterocyclic carbene ligands with the dithienylethene moiety

AU - Duan, Gongping

AU - Wong, Wing Tak

AU - Yam, Vivian Wing Wah

PY - 2011/10/1

Y1 - 2011/10/1

N2 - A series of half-sandwich type ruthenium(ii) complexes, [(η6-mesitylene)Ru(NHC-L)Cl]PF6 (NHC = N-heterocyclic carbene, L = azole and imine ligand), containing the dithienylethene moiety has been synthesized and characterized by 1H NMR, X-ray crystallography and electronic absorption spectroscopy. These complexes show photochromic properties upon UV photo-irradiation to generate the closed forms of the dithienylethene moiety.

AB - A series of half-sandwich type ruthenium(ii) complexes, [(η6-mesitylene)Ru(NHC-L)Cl]PF6 (NHC = N-heterocyclic carbene, L = azole and imine ligand), containing the dithienylethene moiety has been synthesized and characterized by 1H NMR, X-ray crystallography and electronic absorption spectroscopy. These complexes show photochromic properties upon UV photo-irradiation to generate the closed forms of the dithienylethene moiety.

UR - https://www.scopus.com/pages/publications/80053356476

U2 - 10.1039/c1nj20161a

DO - 10.1039/c1nj20161a

M3 - Journal article

SN - 1144-0546

VL - 35

SP - 2267

EP - 2278

JO - New Journal of Chemistry

JF - New Journal of Chemistry

IS - 10

ER -

Synthesis and photochromic studies of η⁶-mesitylene ruthenium(ii) complexes bearing N-heterocyclic carbene ligands with the dithienylethene moiety

Abstract

ASJC Scopus subject areas

More information

Other files and links

Fingerprint

Cite this