Synthesis and molecular structure of the triosmium carbonyl cluster [Os3(CO)10{μ-N(H)(C5H3NBr)}{μ-N(C10H13NO)}], containing two types of amido ligands

Wing Tak Wong; Tin Shing Wong

doi:10.1016/S0022-328X(97)00314-8

Synthesis and molecular structure of the triosmium carbonyl cluster [Os₃(CO)₁₀{μ-N(H)(C₅H₃NBr)}{μ-N(C₁₀H₁₃NO)}], containing two types of amido ligands

Wing Tak Wong, Tin Shing Wong

Research output: Journal article publication › Journal article › Academic research › peer-review

9 Citations (Scopus)

Abstract

Treatment of [Os3(CO)10(NCMe)2] with an equivalent amount of 2-(5-bromo-2-pyridyiazo)-5-(diethylamino)phenol (Br-PADAP) in CH2Cl2at room temperature for 1 h afforded a major brown cluster [Os3(CO)10{μ-N(H)(C5H3NBr)}{μ-N(C10H13NO)}]; the compound contains two types of μ-bridging amido ligands across the same Os ⋯ Os edge.

Original language	English
Pages (from-to)	29-33
Number of pages	5
Journal	Journal of Organometallic Chemistry
Volume	542
Issue number	1
DOIs	https://doi.org/10.1016/S0022-328X(97)00314-8
Publication status	Published - 1 Sep 1997
Externally published	Yes

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
Materials Chemistry

More information

10.1016/S0022-328X(97)00314-8

Cite this

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title = "Synthesis and molecular structure of the triosmium carbonyl cluster [Os3(CO)10{μ-N(H)(C5H3NBr)}{μ-N(C10H13NO)}], containing two types of amido ligands",

abstract = "Treatment of [Os3(CO)10(NCMe)2] with an equivalent amount of 2-(5-bromo-2-pyridyiazo)-5-(diethylamino)phenol (Br-PADAP) in CH2Cl2at room temperature for 1 h afforded a major brown cluster [Os3(CO)10{μ-N(H)(C5H3NBr)}{μ-N(C10H13NO)}]; the compound contains two types of μ-bridging amido ligands across the same Os ⋯ Os edge.",

author = "Wong, {Wing Tak} and Wong, {Tin Shing}",

year = "1997",

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doi = "10.1016/S0022-328X(97)00314-8",

language = "English",

volume = "542",

pages = "29--33",

journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

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Synthesis and molecular structure of the triosmium carbonyl cluster [Os₃(CO)₁₀{μ-N(H)(C₅H₃NBr)}{μ-N(C₁₀H₁₃NO)}], containing two types of amido ligands. / Wong, Wing Tak; Wong, Tin Shing.

In: Journal of Organometallic Chemistry, Vol. 542, No. 1, 01.09.1997, p. 29-33.

Research output: Journal article publication › Journal article › Academic research › peer-review

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AU - Wong, Tin Shing

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N2 - Treatment of [Os3(CO)10(NCMe)2] with an equivalent amount of 2-(5-bromo-2-pyridyiazo)-5-(diethylamino)phenol (Br-PADAP) in CH2Cl2at room temperature for 1 h afforded a major brown cluster [Os3(CO)10{μ-N(H)(C5H3NBr)}{μ-N(C10H13NO)}]; the compound contains two types of μ-bridging amido ligands across the same Os ⋯ Os edge.

AB - Treatment of [Os3(CO)10(NCMe)2] with an equivalent amount of 2-(5-bromo-2-pyridyiazo)-5-(diethylamino)phenol (Br-PADAP) in CH2Cl2at room temperature for 1 h afforded a major brown cluster [Os3(CO)10{μ-N(H)(C5H3NBr)}{μ-N(C10H13NO)}]; the compound contains two types of μ-bridging amido ligands across the same Os ⋯ Os edge.

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