Synthesis and molecular structure of the triosmium carbonyl cluster [Os3(CO)10{μ-N(H)(C5H3NBr)}{μ-N(C10H13NO)}], containing two types of amido ligands

Wing Tak Wong, Tin Shing Wong

Research output: Journal article publicationJournal articleAcademic researchpeer-review

9 Citations (Scopus)

Abstract

Treatment of [Os3(CO)10(NCMe)2] with an equivalent amount of 2-(5-bromo-2-pyridyiazo)-5-(diethylamino)phenol (Br-PADAP) in CH2Cl2at room temperature for 1 h afforded a major brown cluster [Os3(CO)10{μ-N(H)(C5H3NBr)}{μ-N(C10H13NO)}]; the compound contains two types of μ-bridging amido ligands across the same Os ⋯ Os edge.
Original languageEnglish
Pages (from-to)29-33
Number of pages5
JournalJournal of Organometallic Chemistry
Volume542
Issue number1
DOIs
Publication statusPublished - 1 Sep 1997
Externally publishedYes

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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