Synthesis and crystal structures of copper(I) iodide complexes chelating with bis(ethylamidophosphine)

Yat Li, Ka Fu Yung, Hoi Shan Chan, Wing Tak Wong

Research output: Journal article publicationJournal articleAcademic researchpeer-review

17 Citations (Scopus)

Abstract

Two copper(I) iodide complexes with polydentate bis(ethylamidophosphine) ligands were synthesized, characterized with crystal structures. They include a dimeric complex [Cu(μ-I)(CH2NHCOC2H4PPh2)2]21 containing a planar Cu2I2rhombohedron with two doubly bridged ligands and a tetrameric complex {Cu4(μ-I)4[(CH2NHCOC2H4PPh2)2]2} 3 with all the coppers and iodines forming a highly distorted cubane geometry.
Original languageEnglish
Pages (from-to)1451-1453
Number of pages3
JournalInorganic Chemistry Communications
Volume6
Issue number12
DOIs
Publication statusPublished - 1 Jan 2003
Externally publishedYes

Keywords

  • Bis(ethylamidophosphine)
  • Copper(I) iodide complex
  • Crystal structure
  • Cubane

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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