Synthesis and crystal structures of copper(I) iodide complexes chelating with bis(ethylamidophosphine)

Yat Li; Ka Fu Yung; Hoi Shan Chan; Wing Tak Wong

doi:10.1016/j.inoche.2003.09.003

Synthesis and crystal structures of copper(I) iodide complexes chelating with bis(ethylamidophosphine)

Yat Li, Ka Fu Yung, Hoi Shan Chan, Wing Tak Wong

Research output: Journal article publication › Journal article › Academic research › peer-review

18 Citations (Scopus)

Abstract

Two copper(I) iodide complexes with polydentate bis(ethylamidophosphine) ligands were synthesized, characterized with crystal structures. They include a dimeric complex [Cu(μ-I)(CH2NHCOC2H4PPh2)2]21 containing a planar Cu2I2rhombohedron with two doubly bridged ligands and a tetrameric complex {Cu4(μ-I)4[(CH2NHCOC2H4PPh2)2]2} 3 with all the coppers and iodines forming a highly distorted cubane geometry.

Original language	English
Pages (from-to)	1451-1453
Number of pages	3
Journal	Inorganic Chemistry Communications
Volume	6
Issue number	12
DOIs	https://doi.org/10.1016/j.inoche.2003.09.003
Publication status	Published - 1 Jan 2003
Externally published	Yes

Keywords

Bis(ethylamidophosphine)
Copper(I) iodide complex
Crystal structure
Cubane

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/j.inoche.2003.09.003

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title = "Synthesis and crystal structures of copper(I) iodide complexes chelating with bis(ethylamidophosphine)",

abstract = "Two copper(I) iodide complexes with polydentate bis(ethylamidophosphine) ligands were synthesized, characterized with crystal structures. They include a dimeric complex [Cu(μ-I)(CH2NHCOC2H4PPh2)2]21 containing a planar Cu2I2rhombohedron with two doubly bridged ligands and a tetrameric complex {Cu4(μ-I)4[(CH2NHCOC2H4PPh2)2]2} 3 with all the coppers and iodines forming a highly distorted cubane geometry.",

keywords = "Bis(ethylamidophosphine), Copper(I) iodide complex, Crystal structure, Cubane",

author = "Yat Li and Yung, {Ka Fu} and Chan, {Hoi Shan} and Wong, {Wing Tak}",

year = "2003",

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doi = "10.1016/j.inoche.2003.09.003",

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T1 - Synthesis and crystal structures of copper(I) iodide complexes chelating with bis(ethylamidophosphine)

AU - Li, Yat

AU - Yung, Ka Fu

AU - Chan, Hoi Shan

AU - Wong, Wing Tak

PY - 2003/1/1

Y1 - 2003/1/1

N2 - Two copper(I) iodide complexes with polydentate bis(ethylamidophosphine) ligands were synthesized, characterized with crystal structures. They include a dimeric complex [Cu(μ-I)(CH2NHCOC2H4PPh2)2]21 containing a planar Cu2I2rhombohedron with two doubly bridged ligands and a tetrameric complex {Cu4(μ-I)4[(CH2NHCOC2H4PPh2)2]2} 3 with all the coppers and iodines forming a highly distorted cubane geometry.

AB - Two copper(I) iodide complexes with polydentate bis(ethylamidophosphine) ligands were synthesized, characterized with crystal structures. They include a dimeric complex [Cu(μ-I)(CH2NHCOC2H4PPh2)2]21 containing a planar Cu2I2rhombohedron with two doubly bridged ligands and a tetrameric complex {Cu4(μ-I)4[(CH2NHCOC2H4PPh2)2]2} 3 with all the coppers and iodines forming a highly distorted cubane geometry.

KW - Bis(ethylamidophosphine)

KW - Copper(I) iodide complex

KW - Crystal structure

KW - Cubane

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U2 - 10.1016/j.inoche.2003.09.003

DO - 10.1016/j.inoche.2003.09.003

M3 - Journal article

SN - 1387-7003

VL - 6

SP - 1451

EP - 1453

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

IS - 12

ER -

Synthesis and crystal structures of copper(I) iodide complexes chelating with bis(ethylamidophosphine)

Abstract

Keywords

ASJC Scopus subject areas

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