Synthesis and crystal structure of an imidochromium(V) complex with a thioether macrocyclic ligand

Wa Hung Leung; Man Ching Wu; Terry K.T. Wong; Wing Tak Wong

doi:10.1016/S0020-1693(00)00067-0

Synthesis and crystal structure of an imidochromium(V) complex with a thioether macrocyclic ligand

Wa Hung Leung, Man Ching Wu, Terry K.T. Wong, Wing Tak Wong

Research output: Journal article publication › Journal article › Academic research › peer-review

9 Citations (Scopus)

Abstract

Reaction of [Cr(NBu(t))Cl3(dme)] (dme = 1,2-dimethoxyethane) with 1,4,7-trithiacyclononane ([9]aneS3) followed by treatment with Ag(CF3SO3) leads to the isolation of [Cr(N(t)Bu)([9]aneS3)Cl2](CF3SO3), which has been characterized by X-ray crystallography. The Cr-N, average Cr-S, and average Cr-Cl distances are 1.640(4), 2.431, and 2.273 Å, respectively; the Cr-N-C angle being 173.2(4)°. (C) 2000 Elsevier Science S.A.

Original language	English
Pages (from-to)	134-136
Number of pages	3
Journal	Inorganica Chimica Acta
Volume	304
Issue number	1
DOIs	https://doi.org/10.1016/S0020-1693(00)00067-0
Publication status	Published - 15 Jun 2000
Externally published	Yes

Keywords

Chromium complexes
Crystal structures
Imido complexes
Macrocyclic ligand complexes
Thioether complexes

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

More information

10.1016/S0020-1693(00)00067-0

Cite this

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title = "Synthesis and crystal structure of an imidochromium(V) complex with a thioether macrocyclic ligand",

abstract = "Reaction of [Cr(NBu(t))Cl3(dme)] (dme = 1,2-dimethoxyethane) with 1,4,7-trithiacyclononane ([9]aneS3) followed by treatment with Ag(CF3SO3) leads to the isolation of [Cr(N(t)Bu)([9]aneS3)Cl2](CF3SO3), which has been characterized by X-ray crystallography. The Cr-N, average Cr-S, and average Cr-Cl distances are 1.640(4), 2.431, and 2.273 {\AA}, respectively; the Cr-N-C angle being 173.2(4)°. (C) 2000 Elsevier Science S.A.",

keywords = "Chromium complexes, Crystal structures, Imido complexes, Macrocyclic ligand complexes, Thioether complexes",

author = "Leung, {Wa Hung} and Wu, {Man Ching} and Wong, {Terry K.T.} and Wong, {Wing Tak}",

year = "2000",

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doi = "10.1016/S0020-1693(00)00067-0",

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TY - JOUR

T1 - Synthesis and crystal structure of an imidochromium(V) complex with a thioether macrocyclic ligand

AU - Leung, Wa Hung

AU - Wu, Man Ching

AU - Wong, Terry K.T.

AU - Wong, Wing Tak

PY - 2000/6/15

Y1 - 2000/6/15

N2 - Reaction of [Cr(NBu(t))Cl3(dme)] (dme = 1,2-dimethoxyethane) with 1,4,7-trithiacyclononane ([9]aneS3) followed by treatment with Ag(CF3SO3) leads to the isolation of [Cr(N(t)Bu)([9]aneS3)Cl2](CF3SO3), which has been characterized by X-ray crystallography. The Cr-N, average Cr-S, and average Cr-Cl distances are 1.640(4), 2.431, and 2.273 Å, respectively; the Cr-N-C angle being 173.2(4)°. (C) 2000 Elsevier Science S.A.

AB - Reaction of [Cr(NBu(t))Cl3(dme)] (dme = 1,2-dimethoxyethane) with 1,4,7-trithiacyclononane ([9]aneS3) followed by treatment with Ag(CF3SO3) leads to the isolation of [Cr(N(t)Bu)([9]aneS3)Cl2](CF3SO3), which has been characterized by X-ray crystallography. The Cr-N, average Cr-S, and average Cr-Cl distances are 1.640(4), 2.431, and 2.273 Å, respectively; the Cr-N-C angle being 173.2(4)°. (C) 2000 Elsevier Science S.A.

KW - Chromium complexes

KW - Crystal structures

KW - Imido complexes

KW - Macrocyclic ligand complexes

KW - Thioether complexes

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U2 - 10.1016/S0020-1693(00)00067-0

DO - 10.1016/S0020-1693(00)00067-0

M3 - Journal article

SN - 0020-1693

VL - 304

SP - 134

EP - 136

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

IS - 1

ER -

Synthesis and crystal structure of an imidochromium(V) complex with a thioether macrocyclic ligand

Abstract

Keywords

ASJC Scopus subject areas

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