Synthesis and crystal structure of an imidochromium(V) complex with a thioether macrocyclic ligand

Wa Hung Leung, Man Ching Wu, Terry K.T. Wong, Wing Tak Wong

Research output: Journal article publicationJournal articleAcademic researchpeer-review

9 Citations (Scopus)

Abstract

Reaction of [Cr(NBu(t))Cl3(dme)] (dme = 1,2-dimethoxyethane) with 1,4,7-trithiacyclononane ([9]aneS3) followed by treatment with Ag(CF3SO3) leads to the isolation of [Cr(N(t)Bu)([9]aneS3)Cl2](CF3SO3), which has been characterized by X-ray crystallography. The Cr-N, average Cr-S, and average Cr-Cl distances are 1.640(4), 2.431, and 2.273 Å, respectively; the Cr-N-C angle being 173.2(4)°. (C) 2000 Elsevier Science S.A.
Original languageEnglish
Pages (from-to)134-136
Number of pages3
JournalInorganica Chimica Acta
Volume304
Issue number1
DOIs
Publication statusPublished - 15 Jun 2000
Externally publishedYes

Keywords

  • Chromium complexes
  • Crystal structures
  • Imido complexes
  • Macrocyclic ligand complexes
  • Thioether complexes

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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