Synthesis and comparative anion binding profiles of two di-aqua Eu(iii) complexes

Daniela Imperio; Giovanni B. Giovenzana; Ga Lai Law; David Parker; James W. Walton

doi:10.1039/c0dt00773k

Synthesis and comparative anion binding profiles of two di-aqua Eu(iii) complexes

Daniela Imperio, Giovanni B. Giovenzana, Ga Lai Law, David Parker, James W. Walton

Research output: Journal article publication › Journal article › Academic research › peer-review

18 Citations (Scopus)

Abstract

Two di-aqua Eu(iii) complexes of heptadentate ligands are reported that show differing reactivity profiles towards various anions; a cationic complex with two azaxanthone moieties exhibits pronounced selectivity towards bicarbonate with an affinity constant, logK = 2.65 (295 K, 0.1 M NaCl).

Original language	English
Pages (from-to)	9897-9903
Number of pages	7
Journal	Dalton Transactions
Volume	39
Issue number	41
DOIs	https://doi.org/10.1039/c0dt00773k
Publication status	Published - 7 Nov 2010
Externally published	Yes

ASJC Scopus subject areas

Inorganic Chemistry

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10.1039/c0dt00773k

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title = "Synthesis and comparative anion binding profiles of two di-aqua Eu(iii) complexes",

abstract = "Two di-aqua Eu(iii) complexes of heptadentate ligands are reported that show differing reactivity profiles towards various anions; a cationic complex with two azaxanthone moieties exhibits pronounced selectivity towards bicarbonate with an affinity constant, logK = 2.65 (295 K, 0.1 M NaCl).",

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T1 - Synthesis and comparative anion binding profiles of two di-aqua Eu(iii) complexes

AU - Imperio, Daniela

AU - Giovenzana, Giovanni B.

AU - Law, Ga Lai

AU - Parker, David

AU - Walton, James W.

PY - 2010/11/7

Y1 - 2010/11/7

N2 - Two di-aqua Eu(iii) complexes of heptadentate ligands are reported that show differing reactivity profiles towards various anions; a cationic complex with two azaxanthone moieties exhibits pronounced selectivity towards bicarbonate with an affinity constant, logK = 2.65 (295 K, 0.1 M NaCl).

AB - Two di-aqua Eu(iii) complexes of heptadentate ligands are reported that show differing reactivity profiles towards various anions; a cationic complex with two azaxanthone moieties exhibits pronounced selectivity towards bicarbonate with an affinity constant, logK = 2.65 (295 K, 0.1 M NaCl).

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U2 - 10.1039/c0dt00773k

DO - 10.1039/c0dt00773k

M3 - Journal article

SN - 1477-9226

VL - 39

SP - 9897

EP - 9903

JO - Dalton Transactions

JF - Dalton Transactions

IS - 41

ER -

Synthesis and comparative anion binding profiles of two di-aqua Eu(iii) complexes

Abstract

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