Synthesis and characterization of triosmium-dipalladium mixed-metal cluster. Crystal structure of [{(bipy)Pd}2Os3(CO)12]

Suzanna Chan; Wing Tak Wong

doi:10.1016/0022-328X(94)05281-F

Synthesis and characterization of triosmium-dipalladium mixed-metal cluster. Crystal structure of [{(bipy)Pd}₂Os₃(CO)₁₂]

Suzanna Chan, Wing Tak Wong

Research output: Journal article publication › Journal article › Academic research › peer-review

17 Citations (Scopus)

Abstract

The cluster [H2Os3(CO)10] reacts with [(bipy)Pd(CO2Me2] to give [(bipy)Pd2Os3(CO)12], 1, in moderate yield; an X-ray structure analysis of 1 reveals an edge bridging square metal core.

Original language	English
Journal	Journal of Organometallic Chemistry
Volume	489
Issue number	1-2
DOIs	https://doi.org/10.1016/0022-328X(94)05281-F
Publication status	Published - 8 Mar 1995
Externally published	Yes

Keywords

Bipyridine
Carbonyl
Crystal structure
Osmium
Palladium

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
Materials Chemistry

More information

10.1016/0022-328X(94)05281-F

Cite this

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title = "Synthesis and characterization of triosmium-dipalladium mixed-metal cluster. Crystal structure of [{(bipy)Pd}2Os3(CO)12]",

abstract = "The cluster [H2Os3(CO)10] reacts with [(bipy)Pd(CO2Me2] to give [(bipy)Pd2Os3(CO)12], 1, in moderate yield; an X-ray structure analysis of 1 reveals an edge bridging square metal core.",

keywords = "Bipyridine, Carbonyl, Crystal structure, Osmium, Palladium",

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AU - Chan, Suzanna

AU - Wong, Wing Tak

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Y1 - 1995/3/8

N2 - The cluster [H2Os3(CO)10] reacts with [(bipy)Pd(CO2Me2] to give [(bipy)Pd2Os3(CO)12], 1, in moderate yield; an X-ray structure analysis of 1 reveals an edge bridging square metal core.

AB - The cluster [H2Os3(CO)10] reacts with [(bipy)Pd(CO2Me2] to give [(bipy)Pd2Os3(CO)12], 1, in moderate yield; an X-ray structure analysis of 1 reveals an edge bridging square metal core.

KW - Bipyridine

KW - Carbonyl

KW - Crystal structure

KW - Osmium

KW - Palladium

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DO - 10.1016/0022-328X(94)05281-F

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JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

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