Synthesis and characterization of triosmium clusters containing the 2-(benzylthio)benzoyl ligand

Siu Ming Lee; Kung Kai Cheung; Wing Tak Wong

doi:10.1016/0022-328X(95)05430-W

Synthesis and characterization of triosmium clusters containing the 2-(benzylthio)benzoyl ligand

Siu Ming Lee, Kung Kai Cheung, Wing Tak Wong

Research output: Journal article publication › Journal article › Academic research › peer-review

9 Citations (Scopus)

Abstract

Reaction of [Os3(CO)10(MeCN)2] with an equimolar proportion of 2-(benzylthio)-benzaldehyde (1) gives three new compounds: two yellow isomers of [Os3(CO)10(μ-H)(C14H11OS)] (2a and 2b) and an orange crystalline compound [Os3(CO)9(μ-H)C14H11OS)] (3). The molecular structures of 2b and 3 are presented. Two different kinds of bonding mode of the ligand were observed, bidentate through S and C(O) in 2 and terdentate through S, C(O) and O in 3.

Original language	English
Pages (from-to)	273-278
Number of pages	6
Journal	Journal of Organometallic Chemistry
Volume	494
Issue number	1-2
DOIs	https://doi.org/10.1016/0022-328X(95)05430-W
Publication status	Published - 31 May 1995
Externally published	Yes

Keywords

Acyl
Carbonyl
Cluster
Crystal structure
Osmium

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/0022-328X(95)05430-W

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title = "Synthesis and characterization of triosmium clusters containing the 2-(benzylthio)benzoyl ligand",

abstract = "Reaction of [Os3(CO)10(MeCN)2] with an equimolar proportion of 2-(benzylthio)-benzaldehyde (1) gives three new compounds: two yellow isomers of [Os3(CO)10(μ-H)(C14H11OS)] (2a and 2b) and an orange crystalline compound [Os3(CO)9(μ-H)C14H11OS)] (3). The molecular structures of 2b and 3 are presented. Two different kinds of bonding mode of the ligand were observed, bidentate through S and C(O) in 2 and terdentate through S, C(O) and O in 3.",

keywords = "Acyl, Carbonyl, Cluster, Crystal structure, Osmium",

author = "Lee, {Siu Ming} and Cheung, {Kung Kai} and Wong, {Wing Tak}",

year = "1995",

month = may,

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doi = "10.1016/0022-328X(95)05430-W",

language = "English",

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pages = "273--278",

journal = "Journal of Organometallic Chemistry",

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TY - JOUR

T1 - Synthesis and characterization of triosmium clusters containing the 2-(benzylthio)benzoyl ligand

AU - Lee, Siu Ming

AU - Cheung, Kung Kai

AU - Wong, Wing Tak

PY - 1995/5/31

Y1 - 1995/5/31

N2 - Reaction of [Os3(CO)10(MeCN)2] with an equimolar proportion of 2-(benzylthio)-benzaldehyde (1) gives three new compounds: two yellow isomers of [Os3(CO)10(μ-H)(C14H11OS)] (2a and 2b) and an orange crystalline compound [Os3(CO)9(μ-H)C14H11OS)] (3). The molecular structures of 2b and 3 are presented. Two different kinds of bonding mode of the ligand were observed, bidentate through S and C(O) in 2 and terdentate through S, C(O) and O in 3.

AB - Reaction of [Os3(CO)10(MeCN)2] with an equimolar proportion of 2-(benzylthio)-benzaldehyde (1) gives three new compounds: two yellow isomers of [Os3(CO)10(μ-H)(C14H11OS)] (2a and 2b) and an orange crystalline compound [Os3(CO)9(μ-H)C14H11OS)] (3). The molecular structures of 2b and 3 are presented. Two different kinds of bonding mode of the ligand were observed, bidentate through S and C(O) in 2 and terdentate through S, C(O) and O in 3.

KW - Acyl

KW - Carbonyl

KW - Cluster

KW - Crystal structure

KW - Osmium

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U2 - 10.1016/0022-328X(95)05430-W

DO - 10.1016/0022-328X(95)05430-W

M3 - Journal article

SN - 0022-328X

VL - 494

SP - 273

EP - 278

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 1-2

ER -

Synthesis and characterization of triosmium clusters containing the 2-(benzylthio)benzoyl ligand

Abstract

Keywords

ASJC Scopus subject areas

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