Synthesis and characterization of triosmium clusters containing the 2-(benzylthio)benzoyl ligand

Siu Ming Lee, Kung Kai Cheung, Wing Tak Wong

Research output: Journal article publicationJournal articleAcademic researchpeer-review

8 Citations (Scopus)

Abstract

Reaction of [Os3(CO)10(MeCN)2] with an equimolar proportion of 2-(benzylthio)-benzaldehyde (1) gives three new compounds: two yellow isomers of [Os3(CO)10(μ-H)(C14H11OS)] (2a and 2b) and an orange crystalline compound [Os3(CO)9(μ-H)C14H11OS)] (3). The molecular structures of 2b and 3 are presented. Two different kinds of bonding mode of the ligand were observed, bidentate through S and C(O) in 2 and terdentate through S, C(O) and O in 3.
Original languageEnglish
Pages (from-to)273-278
Number of pages6
JournalJournal of Organometallic Chemistry
Volume494
Issue number1-2
DOIs
Publication statusPublished - 31 May 1995
Externally publishedYes

Keywords

  • Acyl
  • Carbonyl
  • Cluster
  • Crystal structure
  • Osmium

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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