Synthesis and characterization of triosmium clusters containing a nitrite ligand; crystal and molecular structures of [N(PPh3)2][Os3(CO)10(μ-η2-NO2)] and [Os3(μ-H)(CO)10(μ-η2-NO2)]

Bernard Kwok Man Hui, Wing Tak Wong

Research output: Journal article publicationJournal articleAcademic researchpeer-review

6 Citations (Scopus)

Abstract

The cluster [Os3(CO)10(NCMe)2] reacted with [N(PPh3)2]NO2in CH2Cl2to give a novel red-orange complex [N(PPh3)2][Os3(CO)10(μ-η2-NO2)] in moderate yield, which underwent protonation with HBF4·Et2O in CH2Cl2to give the neutral complex [Os3(μ-H)(CO)10(μ-η2-NO2)] in high yield; X-ray crystal-structure analyses have shown that both clusters contain a μ-η2-bridging nitrite ligand.
Original languageEnglish
Pages (from-to)2177-2178
Number of pages2
JournalJournal of the Chemical Society - Dalton Transactions
Issue number10
DOIs
Publication statusPublished - 21 May 1996
Externally publishedYes

ASJC Scopus subject areas

  • Chemistry(all)

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