Synthesis and characterization of the undecaosmium carbido carbonyl cluster: Crystal and molecular structures of [N(PPh3)2][Os11C(CO)27(μ-Cl)]

Wing Tak Wong

doi:10.1007/BF01169700

Synthesis and characterization of the undecaosmium carbido carbonyl cluster: Crystal and molecular structures of [N(PPh3)2][Os11C(CO)27(μ-Cl)]

Wing Tak Wong

Research output: Journal article publication › Journal article › Academic research › peer-review

2 Citations (Scopus)

Abstract

A chloro-derivative of undecaosmium carbido cluster [Os11C(CO)27(μ-Cl)]-1 anion has been prepared and fully characterized by spectroscopic and crystallographic methods. The structure 1 is an important intermediate for the conversion of [Os11C(CO)27]22 dianion to [OS10C(CO)24]2-3 dianion.

Original language	English
Pages (from-to)	343-346
Number of pages	4
Journal	Journal of Cluster Science
Volume	6
Issue number	2
DOIs	https://doi.org/10.1007/BF01169700
Publication status	Published - 1 Jun 1995
Externally published	Yes

Keywords

μ-bridged chlorol preparation
crystal structure
Undecaosmium carbido cluster

ASJC Scopus subject areas

Inorganic Chemistry

More information

10.1007/BF01169700

Cite this

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abstract = "A chloro-derivative of undecaosmium carbido cluster [Os11C(CO)27(μ-Cl)]-1 anion has been prepared and fully characterized by spectroscopic and crystallographic methods. The structure 1 is an important intermediate for the conversion of [Os11C(CO)27]22 dianion to [OS10C(CO)24]2-3 dianion.",

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Y1 - 1995/6/1

N2 - A chloro-derivative of undecaosmium carbido cluster [Os11C(CO)27(μ-Cl)]-1 anion has been prepared and fully characterized by spectroscopic and crystallographic methods. The structure 1 is an important intermediate for the conversion of [Os11C(CO)27]22 dianion to [OS10C(CO)24]2-3 dianion.

AB - A chloro-derivative of undecaosmium carbido cluster [Os11C(CO)27(μ-Cl)]-1 anion has been prepared and fully characterized by spectroscopic and crystallographic methods. The structure 1 is an important intermediate for the conversion of [Os11C(CO)27]22 dianion to [OS10C(CO)24]2-3 dianion.

KW - μ-bridged chlorol preparation

KW - crystal structure

KW - Undecaosmium carbido cluster

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DO - 10.1007/BF01169700

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Synthesis and characterization of the undecaosmium carbido carbonyl cluster: Crystal and molecular structures of [N(PPh3)2][Os11C(CO)27(μ-Cl)]

Abstract

Keywords

ASJC Scopus subject areas

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