Synthesis and characterization of the undecaosmium carbido carbonyl cluster: Crystal and molecular structures of [N(PPh3)2][Os11C(CO)27(μ-Cl)]

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Abstract

A chloro-derivative of undecaosmium carbido cluster [Os11C(CO)27(μ-Cl)]-1 anion has been prepared and fully characterized by spectroscopic and crystallographic methods. The structure 1 is an important intermediate for the conversion of [Os11C(CO)27]22 dianion to [OS10C(CO)24]2-3 dianion.
Original languageEnglish
Pages (from-to)343-346
Number of pages4
JournalJournal of Cluster Science
Volume6
Issue number2
DOIs
Publication statusPublished - 1 Jun 1995
Externally publishedYes

Keywords

  • μ-bridged chlorol preparation
  • crystal structure
  • Undecaosmium carbido cluster

ASJC Scopus subject areas

  • Inorganic Chemistry

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