Synthesis and characterization of silver(I) complexes [AgL]2[BF4]2and [Ag(OAc)L]∞[L = (CH2NHCOC2H4PPh2)2]

Yat Li; Ka Fu Yung; Hoi Shan Chan; Wing Tak Wong; Wai Kwok Wong; Man Chung Tse

doi:10.1016/j.inoche.2003.08.007

Synthesis and characterization of silver(I) complexes [AgL]₂[BF₄]₂and [Ag(OAc)L]_∞[L = (CH₂NHCOC₂H₄PPh₂)₂]

Yat Li, Ka Fu Yung, Hoi Shan Chan, Wing Tak Wong, Wai Kwok Wong, Man Chung Tse

Research output: Journal article publication › Journal article › Academic research › peer-review

6 Citations (Scopus)

Abstract

The interaction of (CH2NHCOC2H4PPh2)2, L, with one equivalent of AgBF4and AgOAc gave [AgL]2[BF4]21 and [Ag(OAc)L]∞2, respectively. X-ray crystallographic studies showed that the ligand adopts a linear conformation in dimeric complex 1 and a bent conformation in polymeric complex 2. Both compounds exhibited temperature-dependent31P{1H} NMR spectra.

Original language	English
Pages (from-to)	1315-1318
Number of pages	4
Journal	Inorganic Chemistry Communications
Volume	6
Issue number	10
DOIs	https://doi.org/10.1016/j.inoche.2003.08.007
Publication status	Published - 1 Oct 2003
Externally published	Yes

Keywords

Bis(ethylamidophosphine)
Crystal structure
Silver(I) complex
Temperature-dependent P{ H} NMR study 31 1

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

More information

10.1016/j.inoche.2003.08.007

Cite this

@article{8edf6f6a5a6442deba9ace2ffeb430dd,

title = "Synthesis and characterization of silver(I) complexes [AgL]2[BF4]2and [Ag(OAc)L]∞[L = (CH2NHCOC2H4PPh2)2]",

abstract = "The interaction of (CH2NHCOC2H4PPh2)2, L, with one equivalent of AgBF4and AgOAc gave [AgL]2[BF4]21 and [Ag(OAc)L]∞2, respectively. X-ray crystallographic studies showed that the ligand adopts a linear conformation in dimeric complex 1 and a bent conformation in polymeric complex 2. Both compounds exhibited temperature-dependent31P{1H} NMR spectra.",

keywords = "Bis(ethylamidophosphine), Crystal structure, Silver(I) complex, Temperature-dependent P{ H} NMR study 31 1",

author = "Yat Li and Yung, {Ka Fu} and Chan, {Hoi Shan} and Wong, {Wing Tak} and Wong, {Wai Kwok} and Tse, {Man Chung}",

year = "2003",

month = oct,

day = "1",

doi = "10.1016/j.inoche.2003.08.007",

language = "English",

volume = "6",

pages = "1315--1318",

journal = "Inorganic Chemistry Communications",

issn = "1387-7003",

publisher = "Elsevier B.V.",

number = "10",

}

TY - JOUR

T1 - Synthesis and characterization of silver(I) complexes [AgL]2[BF4]2and [Ag(OAc)L]∞[L = (CH2NHCOC2H4PPh2)2]

AU - Li, Yat

AU - Yung, Ka Fu

AU - Chan, Hoi Shan

AU - Wong, Wing Tak

AU - Wong, Wai Kwok

AU - Tse, Man Chung

PY - 2003/10/1

Y1 - 2003/10/1

N2 - The interaction of (CH2NHCOC2H4PPh2)2, L, with one equivalent of AgBF4and AgOAc gave [AgL]2[BF4]21 and [Ag(OAc)L]∞2, respectively. X-ray crystallographic studies showed that the ligand adopts a linear conformation in dimeric complex 1 and a bent conformation in polymeric complex 2. Both compounds exhibited temperature-dependent31P{1H} NMR spectra.

AB - The interaction of (CH2NHCOC2H4PPh2)2, L, with one equivalent of AgBF4and AgOAc gave [AgL]2[BF4]21 and [Ag(OAc)L]∞2, respectively. X-ray crystallographic studies showed that the ligand adopts a linear conformation in dimeric complex 1 and a bent conformation in polymeric complex 2. Both compounds exhibited temperature-dependent31P{1H} NMR spectra.

KW - Bis(ethylamidophosphine)

KW - Crystal structure

KW - Silver(I) complex

KW - Temperature-dependent P{ H} NMR study 31 1

UR - http://www.scopus.com/inward/record.url?scp=0141960382&partnerID=8YFLogxK

U2 - 10.1016/j.inoche.2003.08.007

DO - 10.1016/j.inoche.2003.08.007

M3 - Journal article

SN - 1387-7003

VL - 6

SP - 1315

EP - 1318

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

IS - 10

ER -