Synthesis and characterization of silver(I) complexes [AgL]2[BF4]2and [Ag(OAc)L][L = (CH2NHCOC2H4PPh2)2]

Yat Li, Ka Fu Yung, Hoi Shan Chan, Wing Tak Wong, Wai Kwok Wong, Man Chung Tse

Research output: Journal article publicationJournal articleAcademic researchpeer-review

7 Citations (Scopus)

Abstract

The interaction of (CH2NHCOC2H4PPh2)2, L, with one equivalent of AgBF4and AgOAc gave [AgL]2[BF4]21 and [Ag(OAc)L]∞2, respectively. X-ray crystallographic studies showed that the ligand adopts a linear conformation in dimeric complex 1 and a bent conformation in polymeric complex 2. Both compounds exhibited temperature-dependent31P{1H} NMR spectra.
Original languageEnglish
Pages (from-to)1315-1318
Number of pages4
JournalInorganic Chemistry Communications
Volume6
Issue number10
DOIs
Publication statusPublished - 1 Oct 2003
Externally publishedYes

Keywords

  • Bis(ethylamidophosphine)
  • Crystal structure
  • Silver(I) complex
  • Temperature-dependent P{ H} NMR study 31 1

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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