Synthesis and characterization of oxidized products of Cux (X = Cl, Br) and N,N-dimethylbenzeneethanethioamide

Hegen Zheng, Tianniu Chen, Xiangrong Ye, Xinquan Xin, Wing Tak Wong, Wa Hung Leung

Research output: Journal article publicationJournal articleAcademic researchpeer-review

Abstract

The binuclear complexes Cu2(C]oH12ONS)2X2, where X = Cl, Br, have been synthesized and characterized and the X-ray structure determination of Cu2(C10H12ONS)2Br2is reported. The ligand originally prepared has been oxidized (along with the metal ion) and changed into a bidentate ligand. Copper(II) has a distorted square planar coordination with Cu-S 2.242(2) Å and Cu-Br 2.318(1) Å. In the structure, two Cu atoms are linked by bridging oxygen atoms with Cu-O 1.908(4) Å and Cu-Cu 3.042 Å.
Original languageEnglish
Pages (from-to)425-431
Number of pages7
JournalJournal of Coordination Chemistry
Volume46
Issue number4
Publication statusPublished - 1 Dec 1999
Externally publishedYes

Keywords

  • Copper
  • Oxidization
  • Synthesis
  • X-ray structure

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Materials Chemistry

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