Synthesis and characterization of oxidized products of Cux (X = Cl, Br) and N,N-dimethylbenzeneethanethioamide

Hegen Zheng; Tianniu Chen; Xiangrong Ye; Xinquan Xin; Wing Tak Wong; Wa Hung Leung

Synthesis and characterization of oxidized products of Cux (X = Cl, Br) and N,N-dimethylbenzeneethanethioamide

Hegen Zheng, Tianniu Chen, Xiangrong Ye, Xinquan Xin, Wing Tak Wong, Wa Hung Leung

Research output: Journal article publication › Journal article › Academic research › peer-review

Abstract

The binuclear complexes Cu2(C]oH12ONS)2X2, where X = Cl, Br, have been synthesized and characterized and the X-ray structure determination of Cu2(C10H12ONS)2Br2is reported. The ligand originally prepared has been oxidized (along with the metal ion) and changed into a bidentate ligand. Copper(II) has a distorted square planar coordination with Cu-S 2.242(2) Å and Cu-Br 2.318(1) Å. In the structure, two Cu atoms are linked by bridging oxygen atoms with Cu-O 1.908(4) Å and Cu-Cu 3.042 Å.

Original language	English
Pages (from-to)	425-431
Number of pages	7
Journal	Journal of Coordination Chemistry
Volume	46
Issue number	4
Publication status	Published - 1 Dec 1999
Externally published	Yes

Keywords

Copper
Oxidization
Synthesis
X-ray structure

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Materials Chemistry

Cite this

@article{90c4e8e53a084c31be73ed1afd4caa3f,

title = "Synthesis and characterization of oxidized products of Cux (X = Cl, Br) and N,N-dimethylbenzeneethanethioamide",

abstract = "The binuclear complexes Cu2(C]oH12ONS)2X2, where X = Cl, Br, have been synthesized and characterized and the X-ray structure determination of Cu2(C10H12ONS)2Br2is reported. The ligand originally prepared has been oxidized (along with the metal ion) and changed into a bidentate ligand. Copper(II) has a distorted square planar coordination with Cu-S 2.242(2) {\AA} and Cu-Br 2.318(1) {\AA}. In the structure, two Cu atoms are linked by bridging oxygen atoms with Cu-O 1.908(4) {\AA} and Cu-Cu 3.042 {\AA}.",

keywords = "Copper, Oxidization, Synthesis, X-ray structure",

author = "Hegen Zheng and Tianniu Chen and Xiangrong Ye and Xinquan Xin and Wong, {Wing Tak} and Leung, {Wa Hung}",

year = "1999",

month = dec,

day = "1",

language = "English",

volume = "46",

pages = "425--431",

journal = "Journal of Coordination Chemistry",

issn = "0095-8972",

publisher = "Taylor and Francis Ltd.",

number = "4",

}

Synthesis and characterization of oxidized products of Cux (X = Cl, Br) and N,N-dimethylbenzeneethanethioamide. / Zheng, Hegen; Chen, Tianniu; Ye, Xiangrong; Xin, Xinquan; Wong, Wing Tak; Leung, Wa Hung.

In: Journal of Coordination Chemistry, Vol. 46, No. 4, 01.12.1999, p. 425-431.

Research output: Journal article publication › Journal article › Academic research › peer-review

TY - JOUR

T1 - Synthesis and characterization of oxidized products of Cux (X = Cl, Br) and N,N-dimethylbenzeneethanethioamide

AU - Zheng, Hegen

AU - Chen, Tianniu

AU - Ye, Xiangrong

AU - Xin, Xinquan

AU - Wong, Wing Tak

AU - Leung, Wa Hung

PY - 1999/12/1

Y1 - 1999/12/1

N2 - The binuclear complexes Cu2(C]oH12ONS)2X2, where X = Cl, Br, have been synthesized and characterized and the X-ray structure determination of Cu2(C10H12ONS)2Br2is reported. The ligand originally prepared has been oxidized (along with the metal ion) and changed into a bidentate ligand. Copper(II) has a distorted square planar coordination with Cu-S 2.242(2) Å and Cu-Br 2.318(1) Å. In the structure, two Cu atoms are linked by bridging oxygen atoms with Cu-O 1.908(4) Å and Cu-Cu 3.042 Å.

AB - The binuclear complexes Cu2(C]oH12ONS)2X2, where X = Cl, Br, have been synthesized and characterized and the X-ray structure determination of Cu2(C10H12ONS)2Br2is reported. The ligand originally prepared has been oxidized (along with the metal ion) and changed into a bidentate ligand. Copper(II) has a distorted square planar coordination with Cu-S 2.242(2) Å and Cu-Br 2.318(1) Å. In the structure, two Cu atoms are linked by bridging oxygen atoms with Cu-O 1.908(4) Å and Cu-Cu 3.042 Å.

KW - Copper

KW - Oxidization

KW - Synthesis

KW - X-ray structure

UR - http://www.scopus.com/inward/record.url?scp=8744252727&partnerID=8YFLogxK

M3 - Journal article

VL - 46

SP - 425

EP - 431

JO - Journal of Coordination Chemistry

JF - Journal of Coordination Chemistry

SN - 0095-8972

IS - 4

ER -

Synthesis and characterization of oxidized products of Cux (X = Cl, Br) and N,N-dimethylbenzeneethanethioamide

Abstract

Keywords

ASJC Scopus subject areas

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