Synthesis and characterization of luminescent cyclometalated platinum(II) complexes of 1,3-bis-hetero-azolylbenzenes with tunable color for applications in organic light-emitting devices through extension of π conjugation by variation of the heteroatom

Alan Kwun Wa Chan; Elizabeth Suk Hang Lam; Anthony Yiu Yan Tam; Daniel Ping Kuen Tsang; Wai Han Lam; Mei Yee Chan; Wing Tak Wong; Vivian Wing Wah Yam

doi:10.1002/chem.201301586

Synthesis and characterization of luminescent cyclometalated platinum(II) complexes of 1,3-bis-hetero-azolylbenzenes with tunable color for applications in organic light-emitting devices through extension of π conjugation by variation of the heteroatom

Alan Kwun Wa Chan, Elizabeth Suk Hang Lam, Anthony Yiu Yan Tam, Daniel Ping Kuen Tsang, Wai Han Lam, Mei Yee Chan, Wing Tak Wong, Vivian Wing Wah Yam

Research output: Journal article publication › Journal article › Academic research › peer-review

46 Citations (Scopus)

Abstract

A series of luminescent cyclometalated platinum(II) complexes of N^C^N ligands [N^C^N=2,6-bis(benzoxazol-2'-yl)benzene (bzoxb), 2,6-bis(benzothiazol- 2'-yl)benzene (bzthb), and 2,6-bis(N-alkylnaphthoimidazol-2'-yl)benzene (naphimb)] has been synthesized and characterized. Two of the platinum(II) complexes have been structurally characterized by X-ray crystallography. Their electrochemical, electronic absorption, and luminescence properties have been investigated. In dichloromethane solution at room temperature, the cyclometalated N^C^N platinum(II) complexes exhibited rich luminescence with well-resolved vibronic-structured emission bands. The emission energies of the complexes are found to be closely related to the electronic properties of the N^C^N li

Original language	English
Pages (from-to)	13910-13924
Number of pages	15
Journal	Chemistry - A European Journal
Volume	19
Issue number	41
DOIs	https://doi.org/10.1002/chem.201301586
Publication status	Published - 4 Oct 2013
Externally published	Yes

Keywords

cyclometalation
density functional theory calculation
luminescence
organic light-emitting diodes
platinum

ASJC Scopus subject areas

Chemistry(all)

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10.1002/chem.201301586

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Chan, A. K. W., Lam, E. S. H., Tam, A. Y. Y., Tsang, D. P. K., Lam, W. H., Chan, M. Y., Wong, W. T., & Yam, V. W. W. (2013). Synthesis and characterization of luminescent cyclometalated platinum(II) complexes of 1,3-bis-hetero-azolylbenzenes with tunable color for applications in organic light-emitting devices through extension of π conjugation by variation of the heteroatom. Chemistry - A European Journal, 19(41), 13910-13924. https://doi.org/10.1002/chem.201301586

Chan, Alan Kwun Wa ; Lam, Elizabeth Suk Hang ; Tam, Anthony Yiu Yan et al. / Synthesis and characterization of luminescent cyclometalated platinum(II) complexes of 1,3-bis-hetero-azolylbenzenes with tunable color for applications in organic light-emitting devices through extension of π conjugation by variation of the heteroatom. In: Chemistry - A European Journal. 2013 ; Vol. 19, No. 41. pp. 13910-13924.

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title = "Synthesis and characterization of luminescent cyclometalated platinum(II) complexes of 1,3-bis-hetero-azolylbenzenes with tunable color for applications in organic light-emitting devices through extension of π conjugation by variation of the heteroatom",

abstract = "A series of luminescent cyclometalated platinum(II) complexes of N^C^N ligands [N^C^N=2,6-bis(benzoxazol-2'-yl)benzene (bzoxb), 2,6-bis(benzothiazol- 2'-yl)benzene (bzthb), and 2,6-bis(N-alkylnaphthoimidazol-2'-yl)benzene (naphimb)] has been synthesized and characterized. Two of the platinum(II) complexes have been structurally characterized by X-ray crystallography. Their electrochemical, electronic absorption, and luminescence properties have been investigated. In dichloromethane solution at room temperature, the cyclometalated N^C^N platinum(II) complexes exhibited rich luminescence with well-resolved vibronic-structured emission bands. The emission energies of the complexes are found to be closely related to the electronic properties of the N^C^N li",

keywords = "cyclometalation, density functional theory calculation, luminescence, organic light-emitting diodes, platinum",

author = "Chan, {Alan Kwun Wa} and Lam, {Elizabeth Suk Hang} and Tam, {Anthony Yiu Yan} and Tsang, {Daniel Ping Kuen} and Lam, {Wai Han} and Chan, {Mei Yee} and Wong, {Wing Tak} and Yam, {Vivian Wing Wah}",

year = "2013",

month = oct,

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doi = "10.1002/chem.201301586",

language = "English",

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Chan, AKW, Lam, ESH, Tam, AYY, Tsang, DPK, Lam, WH, Chan, MY, Wong, WT & Yam, VWW 2013, 'Synthesis and characterization of luminescent cyclometalated platinum(II) complexes of 1,3-bis-hetero-azolylbenzenes with tunable color for applications in organic light-emitting devices through extension of π conjugation by variation of the heteroatom', Chemistry - A European Journal, vol. 19, no. 41, pp. 13910-13924. https://doi.org/10.1002/chem.201301586

Synthesis and characterization of luminescent cyclometalated platinum(II) complexes of 1,3-bis-hetero-azolylbenzenes with tunable color for applications in organic light-emitting devices through extension of π conjugation by variation of the heteroatom. / Chan, Alan Kwun Wa; Lam, Elizabeth Suk Hang; Tam, Anthony Yiu Yan et al.

In: Chemistry - A European Journal, Vol. 19, No. 41, 04.10.2013, p. 13910-13924.

Research output: Journal article publication › Journal article › Academic research › peer-review

TY - JOUR

T1 - Synthesis and characterization of luminescent cyclometalated platinum(II) complexes of 1,3-bis-hetero-azolylbenzenes with tunable color for applications in organic light-emitting devices through extension of π conjugation by variation of the heteroatom

AU - Chan, Alan Kwun Wa

AU - Lam, Elizabeth Suk Hang

AU - Tam, Anthony Yiu Yan

AU - Tsang, Daniel Ping Kuen

AU - Lam, Wai Han

AU - Chan, Mei Yee

AU - Wong, Wing Tak

AU - Yam, Vivian Wing Wah

PY - 2013/10/4

Y1 - 2013/10/4

N2 - A series of luminescent cyclometalated platinum(II) complexes of N^C^N ligands [N^C^N=2,6-bis(benzoxazol-2'-yl)benzene (bzoxb), 2,6-bis(benzothiazol- 2'-yl)benzene (bzthb), and 2,6-bis(N-alkylnaphthoimidazol-2'-yl)benzene (naphimb)] has been synthesized and characterized. Two of the platinum(II) complexes have been structurally characterized by X-ray crystallography. Their electrochemical, electronic absorption, and luminescence properties have been investigated. In dichloromethane solution at room temperature, the cyclometalated N^C^N platinum(II) complexes exhibited rich luminescence with well-resolved vibronic-structured emission bands. The emission energies of the complexes are found to be closely related to the electronic properties of the N^C^N li

AB - A series of luminescent cyclometalated platinum(II) complexes of N^C^N ligands [N^C^N=2,6-bis(benzoxazol-2'-yl)benzene (bzoxb), 2,6-bis(benzothiazol- 2'-yl)benzene (bzthb), and 2,6-bis(N-alkylnaphthoimidazol-2'-yl)benzene (naphimb)] has been synthesized and characterized. Two of the platinum(II) complexes have been structurally characterized by X-ray crystallography. Their electrochemical, electronic absorption, and luminescence properties have been investigated. In dichloromethane solution at room temperature, the cyclometalated N^C^N platinum(II) complexes exhibited rich luminescence with well-resolved vibronic-structured emission bands. The emission energies of the complexes are found to be closely related to the electronic properties of the N^C^N li

KW - cyclometalation

KW - density functional theory calculation

KW - luminescence

KW - organic light-emitting diodes

KW - platinum

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DO - 10.1002/chem.201301586

M3 - Journal article

VL - 19

SP - 13910

EP - 13924

JO - Chemistry - A European Journal

JF - Chemistry - A European Journal

SN - 0947-6539

IS - 41

ER -

Chan AKW, Lam ESH, Tam AYY, Tsang DPK, Lam WH, Chan MY et al. Synthesis and characterization of luminescent cyclometalated platinum(II) complexes of 1,3-bis-hetero-azolylbenzenes with tunable color for applications in organic light-emitting devices through extension of π conjugation by variation of the heteroatom. Chemistry - A European Journal. 2013 Oct 4;19(41):13910-13924. https://doi.org/10.1002/chem.201301586

Synthesis and characterization of luminescent cyclometalated platinum(II) complexes of 1,3-bis-hetero-azolylbenzenes with tunable color for applications in organic light-emitting devices through extension of π conjugation by variation of the heteroatom

Abstract

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