Synthesis and characterization of high-nuclearity osmium-rhodium mixed-metal carbonyl clusters; molecular and crystal structures of [Os12Rh9(CO)44(μ3-Cl)]·2CH2Cl2and [Os4Rh3(μ3-H)(CO)14(μ3-CO)(η4-C7H8)2]

Sarah Yeuk Wah Hung; Wing Tak Wong

doi:10.1039/a706080g

Synthesis and characterization of high-nuclearity osmium-rhodium mixed-metal carbonyl clusters; molecular and crystal structures of [Os₁₂Rh₉(CO)₄₄(μ₃-Cl)]·2CH₂Cl₂and [Os₄Rh₃(μ₃-H)(CO)₁₄(μ₃-CO)(η⁴-C₇H₈)₂]

Sarah Yeuk Wah Hung
, Wing Tak Wong

Research output: Journal article publication › Journal article › Academic research › peer-review

16 Citations (Scopus)

Abstract

The anionic triosmium cluster [N(PPh3)2][Os3(μ-H)(CO)11] reacts with [Rh(nbd)Cl)2(nbd = norbornadiene) in the presence of AgPF6to give two new high-nuclearity osmium-rhodium clusters [Os12Rh9(CO)44(μ3-Cl)] 1 and [Os4Rh3(μ3-H)(CO)14(μ3-CO)(η4-C7H8)2] 2 in moderate yields.

Original language	English
Pages (from-to)	2099-2100
Number of pages	2
Journal	Chemical Communications
Issue number	21
DOIs	https://doi.org/10.1039/a706080g
Publication status	Published - 1 Jan 1997
Externally published	Yes

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/a706080g

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@article{ac0b8241c00d4eafa725687ed5a4f50d,

title = "Synthesis and characterization of high-nuclearity osmium-rhodium mixed-metal carbonyl clusters; molecular and crystal structures of [Os12Rh9(CO)44(μ3-Cl)]·2CH2Cl2and [Os4Rh3(μ3-H)(CO)14(μ3-CO)(η4-C7H8)2]",

abstract = "The anionic triosmium cluster [N(PPh3)2][Os3(μ-H)(CO)11] reacts with [Rh(nbd)Cl)2(nbd = norbornadiene) in the presence of AgPF6to give two new high-nuclearity osmium-rhodium clusters [Os12Rh9(CO)44(μ3-Cl)] 1 and [Os4Rh3(μ3-H)(CO)14(μ3-CO)(η4-C7H8)2] 2 in moderate yields.",

author = "Hung, \{Sarah Yeuk Wah\} and Wong, \{Wing Tak\}",

year = "1997",

month = jan,

day = "1",

doi = "10.1039/a706080g",

language = "English",

pages = "2099--2100",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "21",

}

Synthesis and characterization of high-nuclearity osmium-rhodium mixed-metal carbonyl clusters; molecular and crystal structures of [Os₁₂Rh₉(CO)₄₄(μ₃-Cl)]·2CH₂Cl₂and [Os₄Rh₃(μ₃-H)(CO)₁₄(μ₃-CO)(η⁴-C₇H₈)₂]. / Hung, Sarah Yeuk Wah; Wong, Wing Tak.
In: Chemical Communications, No. 21, 01.01.1997, p. 2099-2100.

Research output: Journal article publication › Journal article › Academic research › peer-review

TY - JOUR

T1 - Synthesis and characterization of high-nuclearity osmium-rhodium mixed-metal carbonyl clusters; molecular and crystal structures of [Os12Rh9(CO)44(μ3-Cl)]·2CH2Cl2and [Os4Rh3(μ3-H)(CO)14(μ3-CO)(η4-C7H8)2]

AU - Hung, Sarah Yeuk Wah

AU - Wong, Wing Tak

PY - 1997/1/1

Y1 - 1997/1/1

N2 - The anionic triosmium cluster [N(PPh3)2][Os3(μ-H)(CO)11] reacts with [Rh(nbd)Cl)2(nbd = norbornadiene) in the presence of AgPF6to give two new high-nuclearity osmium-rhodium clusters [Os12Rh9(CO)44(μ3-Cl)] 1 and [Os4Rh3(μ3-H)(CO)14(μ3-CO)(η4-C7H8)2] 2 in moderate yields.

AB - The anionic triosmium cluster [N(PPh3)2][Os3(μ-H)(CO)11] reacts with [Rh(nbd)Cl)2(nbd = norbornadiene) in the presence of AgPF6to give two new high-nuclearity osmium-rhodium clusters [Os12Rh9(CO)44(μ3-Cl)] 1 and [Os4Rh3(μ3-H)(CO)14(μ3-CO)(η4-C7H8)2] 2 in moderate yields.

UR - https://www.scopus.com/pages/publications/0005115073

U2 - 10.1039/a706080g

DO - 10.1039/a706080g

M3 - Journal article

SN - 1359-7345

SP - 2099

EP - 2100

JO - Chemical Communications

JF - Chemical Communications

IS - 21

ER -