Synthesis and characterization of coordination polymers of Zn(II) with 1,3-bis(4-pyridyl)propane and 4,4′-pyridine ligands

Ting Wai Lee; Jasmine Po Kwan Lau; Wing Tak Wong

doi:10.1016/j.poly.2003.12.020

Synthesis and characterization of coordination polymers of Zn(II) with 1,3-bis(4-pyridyl)propane and 4,4′-pyridine ligands

Ting Wai Lee
, Jasmine Po Kwan Lau
, Wing Tak Wong

Research output: Journal article publication › Journal article › Academic research › peer-review

34 Citations (Scopus)

Abstract

Two new metal-coordination polymers, [Zn2(bpy)(OAc)4]n(1) and [Zn(bpp)(NO3)2]n(2) were prepared by the layering method using Zn(II) ions, bpy and bpp ligands, and structurally characterized by single-crystal X-ray diffraction analyses. Complexes 1 and 2 were both found to be one-dimensional coordination polymers. The periodic length of the chain between two alternate Zn(II) ions in compound 1 is 26.92 Å which is more than twice the length of compound 2 (26.92>11.92×2).

Original language	English
Pages (from-to)	999-1002
Number of pages	4
Journal	Polyhedron
Volume	23
Issue number	6
DOIs	https://doi.org/10.1016/j.poly.2003.12.020
Publication status	Published - 25 Mar 2004
Externally published	Yes

Keywords

1,3-Bis(4-pyridyl)propane
4, 4 -Pyridine ′
Polymeric network
X-ray crystallography
Zinc

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

More information

10.1016/j.poly.2003.12.020

Cite this

@article{77f932b956d5488c9c1c0ef5f6ff2122,

title = "Synthesis and characterization of coordination polymers of Zn(II) with 1,3-bis(4-pyridyl)propane and 4,4′-pyridine ligands",

abstract = "Two new metal-coordination polymers, [Zn2(bpy)(OAc)4]n(1) and [Zn(bpp)(NO3)2]n(2) were prepared by the layering method using Zn(II) ions, bpy and bpp ligands, and structurally characterized by single-crystal X-ray diffraction analyses. Complexes 1 and 2 were both found to be one-dimensional coordination polymers. The periodic length of the chain between two alternate Zn(II) ions in compound 1 is 26.92 {\AA} which is more than twice the length of compound 2 (26.92>11.92×2).",

keywords = "1,3-Bis(4-pyridyl)propane, 4, 4 -Pyridine ′, Polymeric network, X-ray crystallography, Zinc",

author = "Lee, \{Ting Wai\} and Lau, \{Jasmine Po Kwan\} and Wong, \{Wing Tak\}",

year = "2004",

month = mar,

day = "25",

doi = "10.1016/j.poly.2003.12.020",

language = "English",

volume = "23",

pages = "999--1002",

journal = "Polyhedron",

issn = "0277-5387",

publisher = "Elsevier Ltd",

number = "6",

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TY - JOUR

T1 - Synthesis and characterization of coordination polymers of Zn(II) with 1,3-bis(4-pyridyl)propane and 4,4′-pyridine ligands

AU - Lee, Ting Wai

AU - Lau, Jasmine Po Kwan

AU - Wong, Wing Tak

PY - 2004/3/25

Y1 - 2004/3/25

N2 - Two new metal-coordination polymers, [Zn2(bpy)(OAc)4]n(1) and [Zn(bpp)(NO3)2]n(2) were prepared by the layering method using Zn(II) ions, bpy and bpp ligands, and structurally characterized by single-crystal X-ray diffraction analyses. Complexes 1 and 2 were both found to be one-dimensional coordination polymers. The periodic length of the chain between two alternate Zn(II) ions in compound 1 is 26.92 Å which is more than twice the length of compound 2 (26.92>11.92×2).

AB - Two new metal-coordination polymers, [Zn2(bpy)(OAc)4]n(1) and [Zn(bpp)(NO3)2]n(2) were prepared by the layering method using Zn(II) ions, bpy and bpp ligands, and structurally characterized by single-crystal X-ray diffraction analyses. Complexes 1 and 2 were both found to be one-dimensional coordination polymers. The periodic length of the chain between two alternate Zn(II) ions in compound 1 is 26.92 Å which is more than twice the length of compound 2 (26.92>11.92×2).

KW - 1,3-Bis(4-pyridyl)propane

KW - 4, 4 -Pyridine ′

KW - Polymeric network

KW - X-ray crystallography

KW - Zinc

UR - https://www.scopus.com/pages/publications/1642284360

U2 - 10.1016/j.poly.2003.12.020

DO - 10.1016/j.poly.2003.12.020

M3 - Journal article

SN - 0277-5387

VL - 23

SP - 999

EP - 1002

JO - Polyhedron

JF - Polyhedron

IS - 6

ER -

Synthesis and characterization of coordination polymers of Zn(II) with 1,3-bis(4-pyridyl)propane and 4,4′-pyridine ligands

Abstract

Keywords

ASJC Scopus subject areas

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