Synthesis and Characterization of a New Binary Deca‐Osmium Carbonyl Cluster Anion—An Intermediate in the Formation of Other High‐Nuclearity Osmium Carbonyl Clusters; Crystal and Molecular Structure of (Ph4P)2 [Os10 (CO)26]

Angelo J. Amoroso; Brian F.G. Johnson; Jack Lewis; Paul R. Raithby; Wing Tak Wong

doi:10.1002/anie.199115051

Synthesis and Characterization of a New Binary Deca‐Osmium Carbonyl Cluster Anion—An Intermediate in the Formation of Other High‐Nuclearity Osmium Carbonyl Clusters; Crystal and Molecular Structure of (Ph₄P)₂ [Os₁₀ (CO)₂₆]

Angelo J. Amoroso, Brian F.G. Johnson, Jack Lewis, Paul R. Raithby, Wing Tak Wong

Research output: Journal article publication › Journal article › Academic research › peer-review

6 Citations (Scopus)

Abstract

The common precursor 1 to the pyrolysis products of [Os3(CO)10(NCMe)2] (2 and 3) was isolated when the reaction was performed under less extreme conditions. The pyrolysis of 1 itself (counterion Ph4P+) at 300oC gave 2 and 3 in good yield, proving its intermediacy in the reaction. The identification of 1 is a key contribution to the understanding of cluster assembly. (Figure Presented.)

Original language	English
Pages (from-to)	1505-1506
Number of pages	2
Journal	Angewandte Chemie International Edition in English
Volume	30
Issue number	11
DOIs	https://doi.org/10.1002/anie.199115051
Publication status	Published - 1 Jan 1991
Externally published	Yes

ASJC Scopus subject areas

Catalysis
Chemistry(all)

More information

10.1002/anie.199115051

Cite this

Amoroso, A. J., Johnson, B. F. G., Lewis, J., Raithby, P. R., & Wong, W. T. (1991). Synthesis and Characterization of a New Binary Deca‐Osmium Carbonyl Cluster Anion—An Intermediate in the Formation of Other High‐Nuclearity Osmium Carbonyl Clusters; Crystal and Molecular Structure of (Ph₄P)₂ [Os₁₀ (CO)₂₆]. Angewandte Chemie International Edition in English, 30(11), 1505-1506. https://doi.org/10.1002/anie.199115051

Amoroso, Angelo J. ; Johnson, Brian F.G. ; Lewis, Jack ; Raithby, Paul R. ; Wong, Wing Tak. / Synthesis and Characterization of a New Binary Deca‐Osmium Carbonyl Cluster Anion—An Intermediate in the Formation of Other High‐Nuclearity Osmium Carbonyl Clusters; Crystal and Molecular Structure of (Ph₄P)₂ [Os₁₀ (CO)₂₆]. In: Angewandte Chemie International Edition in English. 1991 ; Vol. 30, No. 11. pp. 1505-1506.

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abstract = "The common precursor 1 to the pyrolysis products of [Os3(CO)10(NCMe)2] (2 and 3) was isolated when the reaction was performed under less extreme conditions. The pyrolysis of 1 itself (counterion Ph4P+) at 300oC gave 2 and 3 in good yield, proving its intermediacy in the reaction. The identification of 1 is a key contribution to the understanding of cluster assembly. (Figure Presented.)",

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Amoroso, AJ, Johnson, BFG, Lewis, J, Raithby, PR & Wong, WT 1991, 'Synthesis and Characterization of a New Binary Deca‐Osmium Carbonyl Cluster Anion—An Intermediate in the Formation of Other High‐Nuclearity Osmium Carbonyl Clusters; Crystal and Molecular Structure of (Ph₄P)₂ [Os₁₀ (CO)₂₆]', Angewandte Chemie International Edition in English, vol. 30, no. 11, pp. 1505-1506. https://doi.org/10.1002/anie.199115051

Synthesis and Characterization of a New Binary Deca‐Osmium Carbonyl Cluster Anion—An Intermediate in the Formation of Other High‐Nuclearity Osmium Carbonyl Clusters; Crystal and Molecular Structure of (Ph₄P)₂ [Os₁₀ (CO)₂₆]. / Amoroso, Angelo J.; Johnson, Brian F.G.; Lewis, Jack; Raithby, Paul R.; Wong, Wing Tak.

In: Angewandte Chemie International Edition in English, Vol. 30, No. 11, 01.01.1991, p. 1505-1506.

Research output: Journal article publication › Journal article › Academic research › peer-review

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Amoroso AJ, Johnson BFG, Lewis J, Raithby PR, Wong WT. Synthesis and Characterization of a New Binary Deca‐Osmium Carbonyl Cluster Anion—An Intermediate in the Formation of Other High‐Nuclearity Osmium Carbonyl Clusters; Crystal and Molecular Structure of (Ph₄P)₂ [Os₁₀ (CO)₂₆]. Angewandte Chemie International Edition in English. 1991 Jan 1;30(11):1505-1506. https://doi.org/10.1002/anie.199115051