Abstract
The common precursor 1 to the pyrolysis products of [Os3(CO)10(NCMe)2] (2 and 3) was isolated when the reaction was performed under less extreme conditions. The pyrolysis of 1 itself (counterion Ph4P+) at 300oC gave 2 and 3 in good yield, proving its intermediacy in the reaction. The identification of 1 is a key contribution to the understanding of cluster assembly. (Figure Presented.)
Original language | English |
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Pages (from-to) | 1505-1506 |
Number of pages | 2 |
Journal | Angewandte Chemie International Edition in English |
Volume | 30 |
Issue number | 11 |
DOIs | |
Publication status | Published - 1 Jan 1991 |
Externally published | Yes |
ASJC Scopus subject areas
- Catalysis
- Chemistry(all)