Synthesis and characterisation of the carboxylate linked osmium clusters

Angelo J. Amoroso, Brian F.G. Johnson, Jack Lewis, Chi Keung Li, M. Carmen Ramirez de Arellano, Paul R. Raithby, Gregory P. Shields, Wing Tak Wong

Research output: Journal article publicationJournal articleAcademic researchpeer-review

6 Citations (Scopus)

Abstract

Reactions between the activated cluster [Os3(CO)10(NCMe)2] and malonic acid, succinic acid and dicarboxylic acetylene, respectively, lead to the formation of the linked cluster complexes [{Os3H(CO)10}2(CO2CH2CO2)] (1), [{Os3H(CO)10}2(CO2C2H4CO2)] (2), and [{Os3H(CO)10}2(C4O4)] (3) in good yield. Cluster 3 was subsequently treated with [Co2(CO)8] and this results in the addition of a "Co2(CO)6" group giving [{Os3H(CO)10}2(C2O4){Co2(CO)6}] (4). The X-ray crystal structures are reported for 2-4. In each structure the two triangular triosmium units are linked by the carboxylate groups and within each complex the carboxylate groups are chelating and bridge two osmium atoms.
Original languageEnglish
Pages (from-to)3589-3595
Number of pages7
JournalInorganica Chimica Acta
Volume359
Issue number11
DOIs
Publication statusPublished - 1 Aug 2006
Externally publishedYes

Keywords

  • Carbonyl
  • Carboxylate
  • Cobalt
  • Osmium
  • X-ray structure

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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