Synthesis and characterisation of nona-osmium carbonyl clusters; crystal and molecular structure of [(Ph3P)2N] [Os9H(CO)24]

Angelo J. Amoroso, Brian F.G. Johnson, Jack Lewis, Paul R. Raithby, Wing Tak Wong

Research output: Journal article publicationJournal articleAcademic researchpeer-review

13 Citations (Scopus)

Abstract

The anion [Os9H(CO)24]-, 2 has been isolated in moderate yield by the vacuum pyrolysis of [Os3(CO)10(NCMe)2], and has been shown by a single crystal X-ray structure analysis to contain the previously unobserved tricapped octahedral Os9metal core.
Original languageEnglish
Pages (from-to)814-815
Number of pages2
JournalJournal of the Chemical Society, Chemical Communications
Issue number12
DOIs
Publication statusPublished - 1 Dec 1991
Externally publishedYes

ASJC Scopus subject areas

  • Molecular Medicine

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