Synthesis and characterisation of linked triosmium clusters using the bis(diphenylphosphino)acetylene ligand

Brian F.G. Johnson; Jack Lewis; Anju Deepali Massey; Paul R. Raithby; Wing Tak Wong

doi:10.1016/0022-328X(90)80247-W

Synthesis and characterisation of linked triosmium clusters using the bis(diphenylphosphino)acetylene ligand

Brian F.G. Johnson
, Jack Lewis
, Anju Deepali Massey
, Paul R. Raithby
, Wing Tak Wong

Research output: Journal article publication › Journal article › Academic research › peer-review

16 Citations (Scopus)

Abstract

The reaction of Os3(CO)11(NCMe) with bis(diphenylphosphino)acetylene (dppa) at room temperature affords [Os3(CO)11]2(dppa) (1) in good yield, while Os3(CO)10(NCMe)2with an excess of dppa gives [Os3(CO)10(dppa)]3(2) and [Os3(CO)10(dppa)]4(3) in moderate yields. The structure of 1 has been determined by a single crystal X-ray diffraction study.

Original language	English
Journal	Journal of Organometallic Chemistry
Volume	397
Issue number	2
DOIs	https://doi.org/10.1016/0022-328X(90)80247-W
Publication status	Published - 6 Nov 1990
Externally published	Yes

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
Materials Chemistry

More information

10.1016/0022-328X(90)80247-W

Cite this

@article{262e4633028c4de896d941dacd73e0fc,

title = "Synthesis and characterisation of linked triosmium clusters using the bis(diphenylphosphino)acetylene ligand",

abstract = "The reaction of Os3(CO)11(NCMe) with bis(diphenylphosphino)acetylene (dppa) at room temperature affords [Os3(CO)11]2(dppa) (1) in good yield, while Os3(CO)10(NCMe)2with an excess of dppa gives [Os3(CO)10(dppa)]3(2) and [Os3(CO)10(dppa)]4(3) in moderate yields. The structure of 1 has been determined by a single crystal X-ray diffraction study.",

author = "Johnson, \{Brian F.G.\} and Jack Lewis and Massey, \{Anju Deepali\} and Raithby, \{Paul R.\} and Wong, \{Wing Tak\}",

year = "1990",

month = nov,

day = "6",

doi = "10.1016/0022-328X(90)80247-W",

language = "English",

volume = "397",

journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

publisher = "Elsevier B.V.",

number = "2",

}

TY - JOUR

T1 - Synthesis and characterisation of linked triosmium clusters using the bis(diphenylphosphino)acetylene ligand

AU - Johnson, Brian F.G.

AU - Lewis, Jack

AU - Massey, Anju Deepali

AU - Raithby, Paul R.

AU - Wong, Wing Tak

PY - 1990/11/6

Y1 - 1990/11/6

N2 - The reaction of Os3(CO)11(NCMe) with bis(diphenylphosphino)acetylene (dppa) at room temperature affords [Os3(CO)11]2(dppa) (1) in good yield, while Os3(CO)10(NCMe)2with an excess of dppa gives [Os3(CO)10(dppa)]3(2) and [Os3(CO)10(dppa)]4(3) in moderate yields. The structure of 1 has been determined by a single crystal X-ray diffraction study.

AB - The reaction of Os3(CO)11(NCMe) with bis(diphenylphosphino)acetylene (dppa) at room temperature affords [Os3(CO)11]2(dppa) (1) in good yield, while Os3(CO)10(NCMe)2with an excess of dppa gives [Os3(CO)10(dppa)]3(2) and [Os3(CO)10(dppa)]4(3) in moderate yields. The structure of 1 has been determined by a single crystal X-ray diffraction study.

UR - https://www.scopus.com/pages/publications/0012989265

U2 - 10.1016/0022-328X(90)80247-W

DO - 10.1016/0022-328X(90)80247-W

M3 - Journal article

SN - 0022-328X

VL - 397

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 2

ER -

Synthesis and characterisation of linked triosmium clusters using the bis(diphenylphosphino)acetylene ligand

Abstract

ASJC Scopus subject areas

More information

Other files and links

Fingerprint

Cite this